Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/4720
Title: Non-equilibrium structural evolution of the lithium-rich Li1+yMn2O4 cathode within a battery
Authors: Sharma, N
Yu, DH
Zhu, Y
Wu, Y
Peterson, VK
Keywords: Diffractometers
Llthium
Cathodes
Manganese
Neutrons
Powders
Issue Date: 12-Mar-2013
Publisher: American Chemical Society.
Citation: Sharma, N., Yu, D., Zhu, Y., Wu, Y., & Peterson, V. K. (2013). Non-equilibrium structural evolution of the lithium-rich Li1+yMn2O4 cathode within a battery. Chemistry of Materials, 25 (5), 754-760. doi:10.1021/cm303851w
Abstract: Lithium-ion batteries are undergoing rapid development to meet the energy demands of the transportation and renewable energy-generation sectors. The capacity of a lithium-ion battery is dependent on the amount of lithium that can be reversibly incorporated into the cathode. This work directly quantifies the time- and current-dependent lithium transfer within a cathode functioning under conventional charge?discharge cycling. We examine Li1+yMn2O4 under real working conditions using in situ neutron powder diffraction and link the atomic-scale structure to the battery performance. The lithium location and content, oxygen positional parameter, and lattice parameter of the cathode are measured and linked to the battery?s charge/discharge characteristics. Lithium insertion (discharge) differs from extraction (charge), a feature that may explain the relative ease of discharge (compared with charge) of this material. An atomic-scale understanding of cathode functionality, such as revealed here, will direct improvements in battery performance at both the practical and the fundamental level. © 2013, American Chemical Society.
Gov't Doc #: 5165
URI: http://dx.doi.org/10.1021/cm303851w
http://apo.ansto.gov.au/dspace/handle/10238/4720
ISSN: 0897-4756
Appears in Collections:Journal Articles

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