Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/12591
Title: Use of a miniature diamond-anvil cell in a joint x-ray and neutron high-pressure study on copper sulfate pentahydrate
Authors: Novelli, G
Kamenev, KV
Maynard-Casely, HE
Parsons, S
McIntyre, GJ
Keywords: Neutron diffraction
Pressure range mega pa 10-100
Laue method
Copper sulfates
Monocrystals
X-ray diffraction
Inorganic compounds
Intermolecular forces
Crystallization
ANSTO
Issue Date: Jan-2022
Publisher: International Union of Crystallography
Citation: Novelli, G., Kamenev, K. V., Maynard-Casely, H. E., Parsons, S., & McIntyre, G. J. (2022). Use of a miniature diamond-anvil cell in a joint x-ray and neutron high-pressure study on copper sulfate pentahydrate. IUCrJ, 9(1). doi:10.1107/S2052252521010708
Abstract: Single-crystal X-ray and neutron diffraction data are usually collected using separate samples. This is a disadvantage when the sample is studied at high pressure because it is very difficult to achieve exactly the same pressure in two separate experiments, especially if the neutron data are collected using Laue methods where precise absolute values of the unit-cell dimensions cannot be measured to check how close the pressures are. In this study, diffraction data have been collected under the same conditions on the same sample of copper(II) sulfate pentahydrate, using a conventional laboratory diffractometer and source for the X-ray measurements and the Koala single-crystal Laue diffractometer at the ANSTO facility for the neutron measurements. The sample, of dimensions 0.40 × 0.22 × 0.20 mm3 and held at a pressure of 0.71 GPa, was contained in a miniature Merrill–Bassett diamond-anvil cell. The highly penetrating diffracted neutron beams passing through the metal body of the miniature cell as well as through the diamonds yielded data suitable for structure refinement, and compensated for the low completeness of the X-ray measurements, which was only 24% on account of the triclinic symmetry of the sample and the shading of reciprocal space by the cell. The two data-sets were combined in a single `XN' structure refinement in which all atoms, including H atoms, were refined with anisotropic displacement parameters. The precision of the structural parameters was improved by a factor of up to 50% in the XN refinement compared with refinements using the X-ray or neutron data separately. Published under an open-access licence.
URI: https://doi.org/10.1107/S2052252521010708
https://apo.ansto.gov.au/dspace/handle/10238/12591
ISSN: 2052-2525
Appears in Collections:Journal Articles

Files in This Item:
File Description SizeFormat 
fs5200.pdf989.13 kBAdobe PDFThumbnail
View/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.