Neodymium coordination polymers with propionate, succinate and mixed succinate–oxalate ligands: synthesis, structures and spectroscopic characterization

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dc.contributor.authorScales, Nen_AU
dc.contributor.authorZhang, YJen_AU
dc.contributor.authorBhadbhade, MMen_AU
dc.contributor.authorKaratchevtseva, Ien_AU
dc.contributor.authorKong, Len_AU
dc.contributor.authorLumpkin, GRen_AU
dc.contributor.authorLi, Fen_AU
dc.date.accessioned2022-12-02T04:53:07Zen_AU
dc.date.available2022-12-02T04:53:07Zen_AU
dc.date.issued2015-12-14en_AU
dc.date.statistics2022-10-27en_AU
dc.description.abstractThree neodymium (Nd) coordination polymers with propionate, succinate and mixed succinate–oxalate ligands have been synthesized and structurally characterized. Nd2(C3H5O2)6(H2O)3·3H2O (1) has a 1D polymeric structure built with both ninefold and ten-fold coordinated neodymium polyhedra linked through μ2-bridging propionate ligands. Nd2(C4H4O4)3(H2O)2 (2) has a 3D polymeric structure constructed with two distinct ninefold coordinated neodymium polyhedra linked through three types of succinate ligands, two in μ4- and one in μ3-coordination modes. Nd2(C4H4O4)2(C2O4)(H2O)4·3H2O (3) is built with two types of ten-fold coordinated neodymium polyhedra linked through μ4-succinate ligands into 2D undulating layers which are further connected through μ2-oxalate ligands forming a 3D network with channels. Their vibrational modes and thermal stabilities have been further investigated. Crown Copyright © 2015 Published by Elsevier Ltd.en_AU
dc.identifier.citationScales, N., Zhang, Y., Bhadbhade, M., Karatchevtseva, I., Kong, L., Lumpkin, G. R., & Li, F. (2015). Neodymium coordination polymers with propionate, succinate and mixed succinate–oxalate ligands: synthesis, structures and spectroscopic characterization. Polyhedron, 102, 130-136. doi:10.1016/j.poly.2015.07.065en_AU
dc.identifier.issn0277-5387en_AU
dc.identifier.journaltitlePolyhedronen_AU
dc.identifier.pagination130-136en_AU
dc.identifier.urihttps://doi.org/10.1016/j.poly.2015.07.065en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/14131en_AU
dc.identifier.volume102en_AU
dc.language.isoenen_AU
dc.publisherElsevieren_AU
dc.subjectNeodymiumen_AU
dc.subjectPolymersen_AU
dc.subjectRare earthsen_AU
dc.subjectOxalatesen_AU
dc.subjectLigandsen_AU
dc.subjectStabilityen_AU
dc.titleNeodymium coordination polymers with propionate, succinate and mixed succinate–oxalate ligands: synthesis, structures and spectroscopic characterizationen_AU
dc.typeJournal Articleen_AU
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