[Mn-6] under pressure: a combined crystallographic and magnetic study
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Date
2008-03
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley-VCH Verlag Berlin
Abstract
Folding under pressure: High-pressure crystallography of an Mn6 single-molecule magnet reveals dramatic changes in the intramolecular geometry of the magnetic core. These structural changes effect the magnetic properties of the molecule: the magnitude of the ferromagnetic exchange between the metals is decreased, and under extreme pressure switches to antiferromagnetic. © 2008, Wiley-VCH Verlag Berlin
Description
Keywords
Chemistry, Magnetic properties, Manganese, Magnets, Anisotropy, Correlation functions
Citation
Prescimone, A., Milios, C. J., Moggach, S., Warren, J. E., Lennie, A. R., Sanchez-Benitez, J., Kamenev, K., Bircher, R., Murrie, M., Parsons, S., Brechin, E. K., (2008). [Mn-6] under pressure: a combined crystallographic and magnetic study. Angewandte Chemie International Edition, 47(15), 2828-2831. doi:10.1002/anie.200705819