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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/1169

Title: [Mn-6] under pressure: a combined crystallographic and magnetic study.
Authors: Prescimone, A
Milios, CJ
Moggach, S
Warren, JE
Lennie, AR
Sanchez-Benitez, J
Kamenev, K
Bircher, R
Murrie, M
Parsons, S
Brechin, EK
Keywords: Chemistry
Magnetic Properties
Manganese
Magnets
Anisotropy
Correlation Functions
Issue Date: Mar-2008
Publisher: Wiley-VCH Verlag Berlin
Citation: Prescimone, A., Milios, C. J., Moggach, S., Warren, J. E., Lennie, A. R., Sanchez-Benitez, J., et al. (2008). [Mn-6] under pressure: a combined crystallographic and magnetic study. Angewandte Chemie-International Edition, 47(15), 2828-2831.
Abstract: Folding under pressure: High-pressure crystallography of an Mn6 single-molecule magnet reveals dramatic changes in the intramolecular geometry of the magnetic core. These structural changes effect the magnetic properties of the molecule: the magnitude of the ferromagnetic exchange between the metals is decreased, and under extreme pressure switches to antiferromagnetic. © 2008, Wiley-VCH Verlag Berlin
URI: http://dx.doi.org/10.1002/anie.200705819
http://apo.ansto.gov.au/dspace/handle/10238/1169
ISSN: 1433-7851
Appears in Collections:Journal Articles

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