Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide
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Royal Society of Chemistry
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The structure of TcCo(2)O(4) has been determined using a combination of synchrotron X-ray and neutron powder diffraction methods. It has an inverse spinel structure where the Tc occupies the octahedral sites. Both the refined Tc-O distance and X-ray absorption spectra suggest the Tc is predominantly trivalent.
The structure of TcCo(2)O(4) has been determined using a combination of synchrotron X-ray and neutron powder diffraction methods. It has an inverse spinel structure where the Tc occupies the octahedral sites. Both the refined Tc-O distance and X-ray absorption spectra suggest the Tc is predominantly trivalent.© 2011, Royal Society of Chemistry
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Thorogood, G.J., Zhang, Z.M., Hester, J.R., Kennedy, B.J., Ting, J., Glover, C.J., & Johannessen, B. (2011). Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide. Dalton Transactions, 40(41), 10924-10926. doi:10.1039/c1dt10954e