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Please use this identifier to cite or link to this item: http://apo.ansto.gov.au/dspace/handle/10238/3915

Title: Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide
Authors: Thorogood, GJ
Zhang, ZM
Hester, JR
Kennedy, BJ
Ting, J
Glover, CJ
Johannessen, B
Keywords: Cations
Oxides
Synchrotrons
Neutron Diffraction
Vertebrae
X-ray Spectra
Issue Date: 11-Nov-2011
Publisher: Royal Society of Chemistry
Citation: Thorogood, G.J., Zhang, Z.M., Hester, J.R., Kennedy, B.J., Ting, J., Glover, C.J., Johannessen, B. (2011). Structure and cation ordering in spinel-type TcCo2O4. An example of a trivalent technetium oxide. Dalton Transactions, 40(41), 10924-10926.
Abstract: The structure of TcCo(2)O(4) has been determined using a combination of synchrotron X-ray and neutron powder diffraction methods. It has an inverse spinel structure where the Tc occupies the octahedral sites. Both the refined Tc-O distance and X-ray absorption spectra suggest the Tc is predominantly trivalent. The structure of TcCo(2)O(4) has been determined using a combination of synchrotron X-ray and neutron powder diffraction methods. It has an inverse spinel structure where the Tc occupies the octahedral sites. Both the refined Tc-O distance and X-ray absorption spectra suggest the Tc is predominantly trivalent.© 2011, Royal Society of Chemistry
URI: http://dx.doi.org/10.1039/c1dt10954e
http://apo.ansto.gov.au/dspace/handle/10238/3915
ISSN: 1477-9226
Appears in Collections:Journal Articles

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