Surface characterization of Li-substituted compositionally heterogeneous NaLi0.045Cu0.185Fe0.265Mn0.505O2 sodium-ion cathode material

The understanding of surface chemical and structural processes can provide some insights into designing stable sodium cathode materials. Herein, Li-substituted and compositionally heterogeneous NaLi0.045Cu0.185Fe0.265Mn0.505O2 is used as a platform to investigate the interplay between Li substitution, surface chemistry, and battery performance. Li substitution improves the initial discharge capacity and energy density. However, there is no noticeable benefit in the long-term cycling stability of this material. The Li substitution in the transition-metal (TM) layer also seems to influence the transition-metal (TM) 3d–oxygen (O) 2p hybridization. Upon desodiation, the surface of active particles undergoes significant transition-metal reduction, especially Mn. Furthermore, the presence of electrolyte drastically accelerates such surface degradation. In general, the Li-substituted material experiences severe surface degradation, which is partially responsible for the performance degradation upon long-term cycling. While some studies have reported the benefits of Li substitution, the present study suggests that the effectiveness of the Li substitution strategy depends on the TM compositional distribution. More efforts are needed to improve the surface chemistry of Li-substituted sodium cathode materials. © 2019 American Chemical Society

Keywords

Oxides, Hybridization, Sodium, Transition elements, Electric batteries, Cathodes

Citation

Rahman, M. M., Zhang, Y., Xia, S., Kan, W. H., Avdeev, M., Mu, L., Sokaras, D., Kroll, T., Du, X.-W., Nordlund, D., Liu, Y., & Lin, F. (2019). Surface characterization of Li-substituted compositionally heterogeneous NaLi0.045Cu0.185Fe0.265Mn0.505O2 sodium-ion cathode material. The Journal of Physical Chemistry C, 123(18), 11428–11435. doi:10.1021/acs.jpcc.9b01126