Pyrochlore-fluorite transition in Y2Sn2-xZrxO7 - implications for stability

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Date
2011-02-02
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Publisher
Australian Institute of Physics
Abstract
The pyrochlore-fluorite transition is an important factor in determining how materials behave under conditions of irradiation, whether it be as a waste form or as a nuclear material, e.g. ODS additive. Yttrium based materials are often added as oxides to metallic systems, e.g. oxide dispersion strengthened (ODS) steels, which have a wide range of applications. As part of a large programme of research investigating and developing materials which show a high degree of radiation damage resistance, materials based on Y2Sn2-xZrxO7 have been studied. The materials have been examined to determine the order-disorder transition (pyrochlorefluorite), and how this effects the radiation damage resistance, particularly as both end members have previously been shown to be resistant to damage/amorphisation. Results are presented from diffraction and spectroscopic studies showing the degree of order/disorder within the system.
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Keywords
Irradiation, Pyrochlore, Fluorite, Phase transformations, Zirconium, Materials, Yttrium, Physical radiation effects, Waste forms
Citation
de los Reyes, M., Whittle, K. R., Mitchell, M., Ashbrook, S. E., & Lumpkin, G. R. (2011). Pyrochlore-fluorite transition in Y2Sn2-xZrxO7 - implications for stability. Poster presented to the Australian and New Zealand Institutes of Physics 35th Annual Condensed Matter and Materials Meeting, Charles Sturt University, Wagga Wagga, NSW, 2nd - 4th February, 2011. Retrieved from: https://physics.org.au/wp-content/uploads/cmm/2011/