Understanding the cation ordering transition in high-voltage spinel LiNi0.5Mn1.5O4 by doping Li instead of Ni

Simple item page
dc.contributor.authorLee, Jen_AU
dc.contributor.authorDupre, Nen_AU
dc.contributor.authorAvdeev, Men_AU
dc.contributor.authorKang, Ben_AU
dc.date.accessioned2021-02-04T03:29:19Zen_AU
dc.date.available2021-02-04T03:29:19Zen_AU
dc.date.issued2017-07-27en_AU
dc.date.statistics2021-02-02en_AU
dc.description.abstractWe determined how Li doping affects the Ni/Mn ordering in high-voltage spinel LiNi0.5Mn1.5O4(LNMO) by using neutron diffraction, TEM image, electrochemical measurements, and NMR data. The doped Li occupies empty octahedral interstitials (16c site) before the ordering transition, and can move to normal octahedral sites (16d (4b) site) after the transition. This movement strongly affects the Ni/Mn ordering transition because Li at 16c sites blocks the ordering transition pathway and Li at 16d (4b) sites affects electrostatic interactions with transition metals. As a result, Li doping increases in the Ni/Mn disordering without the effect of Mn3+ ions even though the Li-doped LNMO undergoes order-disorder transition at 700 °C. Li doping can control the amount of Ni/Mn disordering in the spinel without the negative effect of Mn3+ ions on the electrochemical property. © 2021 Springer Nature Limited. Provided by the Springer Nature SharedIt content-sharing initiative.en_AU
dc.identifier.articlenumber6728en_AU
dc.identifier.citationLee, J., Dupre, N., Avdeev, M. & Kang, B. (2017). Understanding the cation ordering transition in high-voltage spinel LiNi0.5Mn1.5O4 by doping Li instead of Ni. Scientific Reports, 7, 6728. doi:10.1038/s41598-017-07139-2en_AU
dc.identifier.issn2045-2322en_AU
dc.identifier.journaltitleScientific Reportsen_AU
dc.identifier.urihttps://doi.org/10.1038/s41598-017-07139-2en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/10323en_AU
dc.identifier.volume7en_AU
dc.language.isoenen_AU
dc.publisherSpringer Natureen_AU
dc.subjectRadioisotope batteriesen_AU
dc.subjectEnergyen_AU
dc.subjectCatalysisen_AU
dc.subjectCationsen_AU
dc.subjectCrystal dopingen_AU
dc.subjectLithiumen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectTransmission electron microscopyen_AU
dc.subjectNuclear magnetic resonanceen_AU
dc.titleUnderstanding the cation ordering transition in high-voltage spinel LiNi0.5Mn1.5O4 by doping Li instead of Nien_AU
dc.typeJournal Articleen_AU
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
s41598-017-07139-2 (1).pdf
Size:
2.64 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.63 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Journal Articles