Regulating the coordination environment of mesopore‐confined single atoms from metalloprotein‐MOFs for highly efficient biocatalysis (Adv. Mater. 44/2022)

Abstract

Single-Atom Catalysts

In article number 2205674, Kang Liang and co-workers develop a generalized strategy to construct highly active ferric-centered single-atom catalysts via a biomineralization strategy that enables the homogeneous encapsulation of metalloproteins within metal-organic frameworks followed by pyrolysis. The enhanced activity of the obtained catalysts benefits from the highly dispersed atoms, the mesopores, and the regulated coordination environment of the single-atom active sites induced by the metalloproteins. © 2022 Wiley-VCH GmbH.

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