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https://apo.ansto.gov.au/dspace/handle/10238/9307| Title: | Ionophoric properties of a tetra-tetrazole functionalised calix[4]arene |
| Authors: | D'Alessio, D Skelton, BW Lengkeek, NA Fraser, BH Krause-Heuer, AM Muzzioli, S Stagni, S Massi, M Ogden, MI |
| Keywords: | Tetrazoles Cations Calixarenes Ligands Rare earths Crystal structure Crystallization Synthesis Electrophoresis |
| Issue Date: | 23-Oct-2015 |
| Publisher: | Taylor and Francis Group |
| Citation: | D'Alessio, D., Skelton, B. W., Lengkeek, N. A., Fraser, B. H., Krause-Heuer, A. M., Muzzioli, S., Stagni, S., Massi, M., & Ogden, M. I. (2015). Ionophoric properties of a tetra-tetrazole functionalised calix [4] arene. Supramolecular Chemistry, 27(11-12), 787-791. doi:10.1080/10610278.2015.1075536 |
| Abstract: | The synthesis and characterisation of p-t-butylcalix[4]arene functionalised at the lower rim with four tetrazole moieties is reported. The macrocycle is found to be a poorer ionophore for lanthanoid cations than the bis-tetrazole–substituted analogue. Solution-phase photophysical studies strongly suggested that the cations interacted only weakly with the calixarene ligand. A mixed sodium/triethylammonium salt of the calixarene ligand was crystallised in the presence of lanthanoid cations and structurally characterised. Strong intramolecular interactions are hypothesised to be the cause of the observed behaviour. © 2015 Taylor & Francis |
| Gov't Doc #: | 8704 |
| URI: | http://dx.doi.org/10.1080/10610278.2015.1075536 http://apo.ansto.gov.au/dspace/handle/10238/9307 |
| ISSN: | 1061-0278 |
| Appears in Collections: | Journal Articles |
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