Kinetics vs. thermodynamics: a unique crystal transformation from a uranyl peroxo-nanocluster to a nanoclustered uranyl polyborate

Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/8039

Title:	Kinetics vs. thermodynamics: a unique crystal transformation from a uranyl peroxo-nanocluster to a nanoclustered uranyl polyborate
Authors:	Zhang, Y Bhadbhade, MM Price, JR Karatchevtseva, I Collison, D Lumpkin, GR
Keywords:	Aqueous solutions Monocrystals Boric acid Transformations Crystallization Hydrolysis
Issue Date:	30-Jul-2014
Publisher:	Royal Society of Chemistry
Citation:	Zhang, Y., Bhadbhade, M., Price, J. R., Karatchevtseva, I., Collison, D., & Lumpkin, G. R. (2014). Kinetics vs. thermodynamics: a unique crystal transformation from a uranyl peroxo-nanocluster to a nanoclustered uranyl polyborate. [10.1039/C4RA06970F]. RSC Advances, 4(65), 34244-34247. doi:10.1039/c4ra06970f
Abstract:	A novel method to prepare a nano-clustered uranyl polyborate in aqueous solution at room temperature has been developed. The initially formed kinetically favoured sodium uranyl peroxide yellow crystals transform, in the presence of boric acid, to the thermodynamically stable sodium uranyl polyborate in light yellow-green single crystal form. © Royal Society of Chemistry 2016
Gov't Doc #:	7581
URI:	http://dx.doi.org/10.1039/c4ra06970f http://apo.ansto.gov.au/dspace/handle/10238/8039
ISSN:	2046-2069
Appears in Collections:	Journal Articles

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