Please use this identifier to cite or link to this item:
https://apo.ansto.gov.au/dspace/handle/10238/8039
Title: | Kinetics vs. thermodynamics: a unique crystal transformation from a uranyl peroxo-nanocluster to a nanoclustered uranyl polyborate |
Authors: | Zhang, Y Bhadbhade, M Price, JR Karatchevtseva, I Collison, D Lumpkin, GR |
Keywords: | Aqueous solutions Monocrystals Boric acid Transformations Crystallization Hydrolysis |
Issue Date: | 30-Jul-2014 |
Publisher: | Royal Society of Chemistry |
Citation: | Zhang, Y., Bhadbhade, M., Price, J. R., Karatchevtseva, I., Collison, D., & Lumpkin, G. R. (2014). Kinetics vs. thermodynamics: a unique crystal transformation from a uranyl peroxo-nanocluster to a nanoclustered uranyl polyborate. [10.1039/C4RA06970F]. RSC Advances, 4(65), 34244-34247. doi:10.1039/c4ra06970f |
Abstract: | A novel method to prepare a nano-clustered uranyl polyborate in aqueous solution at room temperature has been developed. The initially formed kinetically favoured sodium uranyl peroxide yellow crystals transform, in the presence of boric acid, to the thermodynamically stable sodium uranyl polyborate in light yellow-green single crystal form. © Royal Society of Chemistry 2016 |
Gov't Doc #: | 7581 |
URI: | http://dx.doi.org/10.1039/c4ra06970f http://apo.ansto.gov.au/dspace/handle/10238/8039 |
ISSN: | 2046-2069 |
Appears in Collections: | Journal Articles |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.