Kinetics vs. thermodynamics: a unique crystal transformation from a uranyl peroxo-nanocluster to a nanoclustered uranyl polyborate

Simple item page
dc.contributor.authorZhang, YJen_AU
dc.contributor.authorBhadbhade, MMen_AU
dc.contributor.authorPrice, JRen_AU
dc.contributor.authorKaratchevtseva, Ien_AU
dc.contributor.authorCollison, Den_AU
dc.contributor.authorLumpkin, GRen_AU
dc.date.accessioned2016-11-07T04:51:49Zen_AU
dc.date.available2016-11-07T04:51:49Zen_AU
dc.date.issued2014-07-30en_AU
dc.date.statistics2016-11-07en_AU
dc.description.abstractA novel method to prepare a nano-clustered uranyl polyborate in aqueous solution at room temperature has been developed. The initially formed kinetically favoured sodium uranyl peroxide yellow crystals transform, in the presence of boric acid, to the thermodynamically stable sodium uranyl polyborate in light yellow-green single crystal form. © Royal Society of Chemistry 2016en_AU
dc.identifier.citationZhang, Y., Bhadbhade, M., Price, J. R., Karatchevtseva, I., Collison, D., & Lumpkin, G. R. (2014). Kinetics vs. thermodynamics: a unique crystal transformation from a uranyl peroxo-nanocluster to a nanoclustered uranyl polyborate. [10.1039/C4RA06970F]. RSC Advances, 4(65), 34244-34247. doi:10.1039/c4ra06970fen_AU
dc.identifier.govdoc7581en_AU
dc.identifier.issn2046-2069en_AU
dc.identifier.issue65en_AU
dc.identifier.journaltitleRSC Advancesen_AU
dc.identifier.pagination34244-34247en_AU
dc.identifier.urihttp://dx.doi.org/10.1039/c4ra06970fen_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/8039en_AU
dc.identifier.volume4en_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectAqueous solutionsen_AU
dc.subjectMonocrystalsen_AU
dc.subjectBoric aciden_AU
dc.subjectTransformationsen_AU
dc.subjectCrystallizationen_AU
dc.subjectHydrolysisen_AU
dc.titleKinetics vs. thermodynamics: a unique crystal transformation from a uranyl peroxo-nanocluster to a nanoclustered uranyl polyborateen_AU
dc.typeJournal Articleen_AU
Files
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Journal Articles