Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/10970
Title: Crystal structure and monoclinic distortion of glaserite-type Ba3MnSi2O8
Authors: Avdeev, M
Xia, Q
Sale, M
Allison, MC
Ling, CD
Keywords: Crystal structure
Phase transformations
Neutron diffraction
Monoclinic lattices
Magnetic susceptibility
Magnetic properties
Issue Date: 1-Oct-2018
Publisher: Elsevier
Citation: Avdeev, M., Xia, Q., Sale, M., Allison, M., & Ling, C. D. (2018). Crystal structure and monoclinic distortion of glaserite-type Ba3MnSi2O8. Journal of Solid State Chemistry, 266, 1-8, doi:10.1016/j.jssc.2018.07.001
Abstract: Crystal structure and magnetic properties of glaserite-type Ba3MnSi2O8 were investigated using variable temperature neutron powder diffraction and magnetometry. At room temperature the composition is hexagonal and the crystal structure is best described by the P-3m1 space group (a~ 5.7 Å, c~ 7.3 Å) with the apical oxygen atom modelled on a split site. On cooling below ~ 250 K the structure undergoes a phase transition into a monoclinic C2/c form (√3ahex, ahex, 2chex, β~ 90°). Analysing diffraction data in terms of symmetry-adapted distortion modes suggests that the transition is primarily driven by increasing in-plane displacements of O1, which in turn results in the coupled tilting of [SiO4] and [MnO6] octahedra and in-plane displacements of Ba1 atoms. Magnetic susceptibility measurements and neutron powder diffraction data show no evidence for long-range magnetic ordering down to 1.6 K, although the development of magnetic diffuse scattering suggests that a magnetic transition may take place at lower temperature. Crown Copyright © 2018 Published by Elsevier Inc.
URI: https://doi.org/10.1016/j.jssc.2018.07.001
https://apo.ansto.gov.au/dspace/handle/10238/10970
ISSN: 0022-4596
Appears in Collections:Journal Articles

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