Magnetic and crystallographic properties of TbCo4B

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The compound TbCo4B was studied using measurements of AC magnetic susceptibility, magnetization and neutron powder diffraction. It is found that this compound orders at TC≈450 K. Each of the two Tb and two Co sublattices orders ferromagnetically. The coupling is ferromagnetic within each pair and ferrimagnetic between pairs. A compensation point at ∼300 K and a spin reorientation between 400 and 430 K were found. © 2006 Elsevier B.V.
Magnetic properties, Neutron diffraction, Rare earths, Borides, Ferromagnetism, Crystallography
Caspi, E. N., Dubman, M., Ettedgui, H., Shaked, H., Melamud, M., Keller, L., & Avdeev, M. (2006). Magnetic and crystallographic properties of TbCo4B. Paper presented at the Eighth International Conference on Neutron Scattering (ICNS 2005), "Neutrons for structure and dynamics - a new era", Sydney, Australia, 27 November to 2 December 2005. In Campbell, S. J., Cadogan, J. M., Furusaka, M., Hauser, N., & James, M. (Eds), Physica B: Condensed Matter, 385–386(Part 1), 339-342, doi:10.1016/j.physb.2006.05.040