Crystal structures and color properties of new complex perovskite oxynitrides AMg0.2Ta0.8O2.6N0.4 (A = Sr, Ba)
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Date
2016-02-26
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Publisher
Royal Society of Chemistry
Abstract
New complex perovskite oxynitrides AMg0.2Ta0.8O2.6N0.4 (A = Sr, Ba) were synthesized by reacting A5Ta4O15 with MgCl2 in flowing NH3. The formation of AMg0.2Ta0.8O2.6N0.4 can be described as the cooperative insertion of Mg2+ + 2N3− and the release of 2O2− from the layered oxide, A5Ta4O15. Rietveld refinement of the neutron and synchrotron X-ray diffraction patterns indicated that BaMg0.2Ta0.8O2.6N0.4 is simple cubic (Pm[3 with combining macron]m) and SrMg0.2Ta0.8O2.6N0.4 is body-centered tetragonal (I4/mcm), isostructural with BaM0.2Ta0.8O2.8N0.2 and SrM0.2Ta0.8O2.8N0.2 (M = Li, Na), respectively. The nitrogen in SrMg0.2Ta0.8O2.6N0.4 is partially ordered favoring the c-axial site over the ab-plane of the tetragonal cell, which is a different O/N order pattern from that of SrLi0.2Ta0.8O2.8N0.2 and SrNa0.2Ta0.8O2.8N0.2. The group of simple and complex perovskites, ATaO2N, ALi0.2Ta0.8O2.8N0.2, ANa0.2Ta0.8O2.8N0.2, and AMg0.2Ta0.8O2.6N0.4 (A = Sr, Ba) covers the band gap range, 1.9–2.4 eV, and the color ranges from yellow to dark brown. © Royal Society of Chemistry 2021
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Keywords
X-ray diffraction, Neutron diffraction, Perovskites, Oxides, Nitrogen, Crystal structure
Citation
Moon, K.-H., Kim, J.-M., Sohn, Y., Cho, D. W., Kim, Y.-I. & Avdeev, M. (2016). Crystal structures and color properties of new complex perovskite oxynitrides AMg0.2Ta0.8O2.6N0.4 (A = Sr, Ba). Dalton Transactions, 45(13), 5614-5621. doi:10.1039/C6DT00310A