Crystal structure of dielectric ceramics in the La(Mg0.5Ti0.5)O3–BaTiO3 system

Please use this identifier to cite or link to this item: https://apo.ansto.gov.au/dspace/handle/10238/10046

Title:	Crystal structure of dielectric ceramics in the La(Mg0.5Ti0.5)O3–BaTiO3 system
Authors:	Avdeev, M Seabra, M Ferreira, V
Keywords:	Crystal structure Dielectric materials X-ray diffraction Ceramics Phase transformations Cations
Issue Date:	31-Jan-2011
Publisher:	Cambridge University Press
Citation:	Avdeev, M., Seabra, M., & Ferreira, V. (2002). Crystal structure of dielectric ceramics in the La(Mg0.5Ti0.5)O3–BaTiO3 system. Journal of Materials Research, 17(5), 1112-1117. doi:10.1557/JMR.2002.0164
Abstract:	The crystal structure of microwave dielectric ceramics in the (1 − x)La(Mg0.5Ti0.5)O3 (LMT)–xBaTiO3 (BT) (0 ≤ x ≤ 0.9) system has been refined by Rietveld method using x-ray powder diffraction data. LMT and BT were found to form a solid solution in the whole compositional range. The increase of BaTiO3 content results in the following sequence of structure transformations of those solid solutions: P21/n (a−a−c+, B-site ordered) → Pbnm (a−a−c+) → I4/mcm (a0a0c−) → Pm3m (a0a0a0). These structural changes are related to the disappearance of B-site cation ordering (x > 0.1), in-phase tilting (x > 0.3), and antiphase tilting (x > 0.5), respectively. © Materials Research Society 2002
URI:	https://doi.org/10.1557/JMR.2002.0164 https://apo.ansto.gov.au/dspace/handle/10238/10046
ISSN:	2044-5326
Appears in Collections:	Journal Articles

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