Lattice response of the porous coordination framework Zn(hba) to guest adsorption

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dc.contributor.authorAuckett, JEen_AU
dc.contributor.authorDharma, ADen_AU
dc.contributor.authorCagnes, MPen_AU
dc.contributor.authorDarwish, TAen_AU
dc.contributor.authorAbrahams, BFen_AU
dc.contributor.authorBarbarao, Ren_AU
dc.contributor.authorHudson, TAen_AU
dc.contributor.authorRobson, Ren_AU
dc.contributor.authorWhite, KFen_AU
dc.contributor.authorPeterson, VKen_AU
dc.date.accessioned2021-08-26T22:30:04Zen_AU
dc.date.available2021-08-26T22:30:04Zen_AU
dc.date.issued2017-09-05en_AU
dc.date.statistics2021-08-26en_AU
dc.description.abstractAnalysis of in situ neutron powder diffraction data collected for the porous framework material Zn(hba) during gas adsorption reveals a two-stage response of the host lattice to increasing CO2 guest concentration, suggesting progressive occupation of multiple CO2 adsorption sites with different binding strengths. The response of the lattice to moderate CH4 guest concentrations is virtually indistinguishable from the response to CO2, demonstrating that the influence of host–guest interactions on the Zn(hba) framework is defined more strongly by the concentration than by the identity of the guests. © International Centre for Diffraction Data 2017en_AU
dc.identifier.citationAuckett, J. E., Dharma, A. D., Cagnes, M. P., Darwish, T. A., Abrahams, B. F., Babarao, R., Hudson, T. A., Robson, R., White, K. F. & Peterson, V. K. (2017). Lattice response of the porous coordination framework Zn (hba) to guest adsorption. Paper presented to the Australian X-ray Analytical Association Workshops, Conference and Exhibition, "Innovation from Characterisation", 5-9 February 2017, Pullman Albert Park, Melbourne, Vic, Australia. In Webster, A. S. & Peterson, V. K. (Eds), Powder Diffraction, 32(S2), S49-S53. doi:10.1017/S0885715617000720en_AU
dc.identifier.conferenceenddate9 February 2017en_AU
dc.identifier.conferencenameAustralian X-ray Analytical Association Workshops, Conference and Exhibition, "Innovation from Characterisation"en_AU
dc.identifier.conferenceplaceMelbourne, Australiaen_AU
dc.identifier.conferencestartdate5 February 2017en_AU
dc.identifier.editorsWebster, A. S. & Peterson, V. K.en_AU
dc.identifier.issn2631-3626en_AU
dc.identifier.issueS2en_AU
dc.identifier.paginationS49-S53en_AU
dc.identifier.urihttps://doi.org/10.1017/S0885715617000720en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/11520en_AU
dc.identifier.volume32en_AU
dc.language.isoenen_AU
dc.publisherCambridge University Pressen_AU
dc.subjectGasesen_AU
dc.subjectSorptionen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectCrystal latticesen_AU
dc.subjectPorosityen_AU
dc.subjectCarbon dioxideen_AU
dc.titleLattice response of the porous coordination framework Zn(hba) to guest adsorptionen_AU
dc.typeConference Paperen_AU
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