Magnetic structure and properties of the rechargeable battery insertion compound Na2FePO4F

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dc.contributor.authorAvdeev, Men_AU
dc.contributor.authorLing, CDen_AU
dc.contributor.authorTan, TTen_AU
dc.contributor.authorLi, Sen_AU
dc.contributor.authorOyama, Gen_AU
dc.contributor.authorYamada, Aen_AU
dc.contributor.authorBarpanda, Pen_AU
dc.date.accessioned2021-01-19T01:07:11Zen_AU
dc.date.available2021-01-19T01:07:11Zen_AU
dc.date.issued2013-12-26en_AU
dc.date.statistics2021-01-11en_AU
dc.description.abstractThe magnetic structure and properties of sodium iron fluorophosphate Na2FePO4F (space group Pbcn), a cathode material for rechargeable batteries, were studied using magnetometry and neutron powder diffraction. The material, which can be described as a quasi-layered structure with zigzag Fe-octahedral chains, develops a long-range antiferromagnetic order below ∼3.4 K. The magnetic structure is rationalized as a super-exchange-driven ferromagnetic ordering of chains running along the a-axis, coupled antiferromagnetically by super-super-exchange via phosphate groups along the c-axis, with ordering along the b-axis likely due to the contribution of dipole–dipole interactions. © 2013 American Chemical Societyen_AU
dc.identifier.citationAvdeev, M., Ling, C. D., Tan, T. T., Li, S., Oyama, G., Yamada, A., & Barpanda, P. (2014) Magnetic structure and properties of the rechargeable battery insertion compound Na2FePO4F. Inorganic Chemistry, 53(2), 682–684. doi:10.1021/ic402513den_AU
dc.identifier.issn1520-510Xen_AU
dc.identifier.issue2en_AU
dc.identifier.journaltitleInorganic Chemistryen_AU
dc.identifier.pagination682-684en_AU
dc.identifier.urihttps://doi.org/10.1021/ic402513den_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/10256en_AU
dc.identifier.volume53en_AU
dc.language.isoenen_AU
dc.publisherAmerican Chemical Societyen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectMagnetic propertiesen_AU
dc.subjectCathodesen_AU
dc.subjectCrystal structureen_AU
dc.subjectAntiferromagnetismen_AU
dc.subjectFerromagnetismen_AU
dc.subjectRadioisotope batteriesen_AU
dc.subjectPhosphatesen_AU
dc.titleMagnetic structure and properties of the rechargeable battery insertion compound Na2FePO4Fen_AU
dc.typeJournal Articleen_AU
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