Effect of oxygen activity on chromium segregation in Cr-doped TiO2 single crystal
dc.contributor.author | Jayamaha, U | en_AU |
dc.contributor.author | Atanacio, AJ | en_AU |
dc.contributor.author | Bak, T | en_AU |
dc.contributor.author | Nowotny, J | en_AU |
dc.contributor.author | Liu, R | en_AU |
dc.date.accessioned | 2020-10-19T23:53:00Z | en_AU |
dc.date.available | 2020-10-19T23:53:00Z | en_AU |
dc.date.issued | 2014-08-30 | en_AU |
dc.date.statistics | 2020-10-15 | en_AU |
dc.description.abstract | The present work determined the effect of chromium segregation on surface and near-surface composition of Cr-doped TiO2 (0.05 at.% Cr) after annealing in oxidising and strongly reducing environments at 1,073 and 1,273 K. The segregation-induced depth profiles were determined by secondary ion mass spectrometry (SIMS). It was observed that annealing in oxidising conditions [p(O2) = 105 Pa] and reducing conditions [10−11 Pa > p(O2) > 10−15 Pa] results in an enrichment and depletion of the surface layer in chromium, respectively. The observed effects may be used for tailoring the surface and near-surface composition in order to impose desired properties. © 2015 Springer Nature Switzerland AG. | en_AU |
dc.identifier.citation | Jayamaha, U., Atanacio, A. J., Bak, T., Nowotny, J., & Liu, R. (2015). Effect of oxygen activity on chromium segregation in Cr-doped TiO 2 single crystal. Ionics, 21(3), 785-790. doi:10.1007/s11581-014-1226-9 | en_AU |
dc.identifier.issn | 0947-7047 | en_AU |
dc.identifier.issue | 3 | en_AU |
dc.identifier.journaltitle | Ionics | en_AU |
dc.identifier.pagination | 785-790 | en_AU |
dc.identifier.uri | https://doi.org/10.1007/s11581-014-1226-9 | en_AU |
dc.identifier.uri | https://apo.ansto.gov.au/dspace/handle/10238/9911 | en_AU |
dc.identifier.volume | 21 | en_AU |
dc.language.iso | en | en_AU |
dc.publisher | Springer Nature | en_AU |
dc.subject | Oxygen | en_AU |
dc.subject | Chromium | en_AU |
dc.subject | Mass spectroscopy | en_AU |
dc.subject | Monocrystals | en_AU |
dc.subject | Titanium | en_AU |
dc.subject | Annealing | en_AU |
dc.title | Effect of oxygen activity on chromium segregation in Cr-doped TiO2 single crystal | en_AU |
dc.type | Journal Article | en_AU |
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