Effect of oxygen activity on chromium segregation in Cr-doped TiO2 single crystal

dc.contributor.authorJayamaha, Uen_AU
dc.contributor.authorAtanacio, AJen_AU
dc.contributor.authorBak, Ten_AU
dc.contributor.authorNowotny, Jen_AU
dc.contributor.authorLiu, Ren_AU
dc.date.accessioned2020-10-19T23:53:00Zen_AU
dc.date.available2020-10-19T23:53:00Zen_AU
dc.date.issued2014-08-30en_AU
dc.date.statistics2020-10-15en_AU
dc.description.abstractThe present work determined the effect of chromium segregation on surface and near-surface composition of Cr-doped TiO2 (0.05 at.% Cr) after annealing in oxidising and strongly reducing environments at 1,073 and 1,273 K. The segregation-induced depth profiles were determined by secondary ion mass spectrometry (SIMS). It was observed that annealing in oxidising conditions [p(O2) = 105 Pa] and reducing conditions [10−11 Pa > p(O2) > 10−15 Pa] results in an enrichment and depletion of the surface layer in chromium, respectively. The observed effects may be used for tailoring the surface and near-surface composition in order to impose desired properties. © 2015 Springer Nature Switzerland AG.en_AU
dc.identifier.citationJayamaha, U., Atanacio, A. J., Bak, T., Nowotny, J., & Liu, R. (2015). Effect of oxygen activity on chromium segregation in Cr-doped TiO 2 single crystal. Ionics, 21(3), 785-790. doi:10.1007/s11581-014-1226-9en_AU
dc.identifier.issn0947-7047en_AU
dc.identifier.issue3en_AU
dc.identifier.journaltitleIonicsen_AU
dc.identifier.pagination785-790en_AU
dc.identifier.urihttps://doi.org/10.1007/s11581-014-1226-9en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/9911en_AU
dc.identifier.volume21en_AU
dc.language.isoenen_AU
dc.publisherSpringer Natureen_AU
dc.subjectOxygenen_AU
dc.subjectChromiumen_AU
dc.subjectMass spectroscopyen_AU
dc.subjectMonocrystalsen_AU
dc.subjectTitaniumen_AU
dc.subjectAnnealingen_AU
dc.titleEffect of oxygen activity on chromium segregation in Cr-doped TiO2 single crystalen_AU
dc.typeJournal Articleen_AU
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