Preferential association of adsorbed uranium with mineral surfaces: a study using analytical electron microscopy

dc.contributor.authorLumpkin, GRen_AU
dc.contributor.authorPayne, TEen_AU
dc.contributor.authorFenton, BRen_AU
dc.contributor.authorWaite, TDen_AU
dc.date.accessioned2023-01-25T00:49:21Zen_AU
dc.date.available2023-01-25T00:49:21Zen_AU
dc.date.issued1999-08-01en_AU
dc.date.statistics2023-01-12en_AU
dc.descriptionMRS Proceedings Online were formerly published by Cambridge University Press and are currently published by Springer Nature.en_AU
dc.description.abstractAnalytical electron microscopy (AEM) has been employed to characterize the distribution of U(VI) on several mineral substrates, including standard kaolinite samples and weathered rock samples from Koongarra, Australia. Results of this study reveal that pre-existing impurity phases play a significant role in the uptake of U(VI) on standard kaolinite samples. Using a natural sample from the weathered zone of the Koongarra uranium deposit, we have also demonstrated that U(VI) sorption is controlled by iron oxyhydroxides (predominantly goethite) which constitute a small fraction of the sample. Limited sorption of U(VI) was observed on the clay minerals of this substrate. Uptake of U(VI) by goethite increases with total uranium content up to the point of uranium precipitation, after which it decreases dramatically. Uranium precipitation is indicated by the appearance of a uranyl oxyhydroxide phase. © 1999 Materials Research Societyen_AU
dc.identifier.booktitleMRS Proceedingsen_AU
dc.identifier.citationLumpkin, G., Payne, T., Fenton, B., & Waite, T. (1999). Preferential association of adsorbed uranium with mineral surfaces: a study using analytical electron microscopy. Paper presented to the 1998 Materials Research Society Fall Meeting, Boston, MA (United States), 30 Nov - 4 Dec 1998. In Lee, J. H. & Wronkiewicz, D. J., (Eds), MRS Proceedings, 556, 1067-1074. doi:10.1557/PROC-556-1067en_AU
dc.identifier.conferenceenddate4 December 1998en_AU
dc.identifier.conferencename1998 Materials Research Society Fall Meetingen_AU
dc.identifier.conferenceplaceBoston, Massachusettsen_AU
dc.identifier.conferencestartdate30 November 1998en_AU
dc.identifier.editorsLee, J. H. & Wronkiewicz, D. J.en_AU
dc.identifier.isbn9781558994621en_AU
dc.identifier.issn0272-9172en_AU
dc.identifier.pagination1067-1074en_AU
dc.identifier.urihttps://doi.org/10.1557/PROC-556-1067en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/14491en_AU
dc.identifier.volume556en_AU
dc.language.isoenen_AU
dc.publisherCambridge University Press/Springer Nature Limiteden_AU
dc.subjectAdsorptionen_AU
dc.subjectClaysen_AU
dc.subjectGoethiteen_AU
dc.subjectKaoliniteen_AU
dc.subjectNatural analogueen_AU
dc.subjectPhase studiesen_AU
dc.subjectRadioactive waste disposalen_AU
dc.subjectSorptive propertiesen_AU
dc.subjectUranyl compoundsen_AU
dc.subjectKoongarra depositen_AU
dc.subjectAustraliaen_AU
dc.subjectElectron microscopyen_AU
dc.subjectNorthern Territoryen_AU
dc.subjectUraniumen_AU
dc.titlePreferential association of adsorbed uranium with mineral surfaces: a study using analytical electron microscopyen_AU
dc.typeConference Paperen_AU
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