Thermal expansion behavior in TcO2. Toward breaking the Tc–Tc bond

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dc.contributor.authorReynolds, EMen_AU
dc.contributor.authorZhang, Zen_AU
dc.contributor.authorAvdeev, Men_AU
dc.contributor.authorThorogood, GJen_AU
dc.contributor.authorPoineau, Fen_AU
dc.contributor.authorCzerwinski, KRen_AU
dc.contributor.authorKimpton, JAen_AU
dc.contributor.authorKennedy, BJen_AU
dc.date.accessioned2021-06-27T22:17:20Zen_AU
dc.date.available2021-06-27T22:17:20Zen_AU
dc.date.issued2017-07-24en_AU
dc.date.statistics2021-05-31en_AU
dc.description.abstractThe structure of TcO2 between 25 and 1000 °C has been determined in situ using X-ray powder diffraction methods and is found to remain monoclinic in space group P21/c. Thermal expansion in TcO2 is highly anisotropic, with negative thermal expansion of the b axis observed above 700 °C. This is the result of an anomalous expansion along the a axis that is a consequence of weakening of the Tc–Tc bonds. © 2017 American Chemical Societyen_AU
dc.identifier.citationReynolds, E., Zhang, Z., Avdeev, M., Thorogood, G. J., Poineau, F., Czerwinski, K. R., Kimpton, J. A., & Kennedy, B. J. (2017). Thermal expansion behavior in TcO2. Toward breaking the Tc–Tc bond. Inorganic Chemistry, 56(15), 9219-9224. doi:10.1021/acs.inorgchem.7b01235en_AU
dc.identifier.issn1520-510Xen_AU
dc.identifier.issue15en_AU
dc.identifier.journaltitleInorganic Chemistryen_AU
dc.identifier.pagination9219-9224en_AU
dc.identifier.urihttps://doi.org/10.1021/acs.inorgchem.7b01235en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/10895en_AU
dc.identifier.volume56en_AU
dc.language.isoenen_AU
dc.publisherAmerican Chemical Societyen_AU
dc.subjectThermal expansionen_AU
dc.subjectOxidesen_AU
dc.subjectCrystal latticesen_AU
dc.subjectPhysical propertiesen_AU
dc.subjectChemical propertiesen_AU
dc.subjectX-ray diffractionen_AU
dc.titleThermal expansion behavior in TcO2. Toward breaking the Tc–Tc bonden_AU
dc.typeJournal Articleen_AU
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