Structure and magnetism in Sr A_xTcO 3 perovskites: importance of the A-site cation

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dc.contributor.authorReynolds, EMen_AU
dc.contributor.authorAvdeev, Men_AU
dc.contributor.authorThorogood, GJen_AU
dc.contributor.authorPoineau, Fen_AU
dc.contributor.authorCzerwinski, KRen_AU
dc.contributor.authorKimpton, JAen_AU
dc.contributor.authorYu, Men_AU
dc.contributor.authorKayser, Pen_AU
dc.contributor.authorKennedy, BJen_AU
dc.date.accessioned2021-07-09T03:31:58Zen_AU
dc.date.available2021-07-09T03:31:58Zen_AU
dc.date.issued2017-02-27en_AU
dc.date.statistics2021-07-02en_AU
dc.description.abstractThe Sr1−xBaxTcO3 (x=0, 0.1, 0.2) oxides were prepared and their solid-state and magnetic structure studied as a function of temperature by x-ray and neutron powder diffraction. The refined Tc moments at room temperature and Néel temperatures for Ba0.1Sr0.9TcO3 and Ba0.2Sr0.8TcO3 were 2.32(14)μβ and 2.11(13)μβ and 714∘C and 702∘C, respectively. In contrast to expectations, the Néel temperature in the series Sr1−xAxTcO3 decreases with increasing Ba content. This observation is consistent with previous experimental measurements for the two series AMO3 (M=Ru, Mn; A=Ca, Sr, Ba) where the maximum magnetic ordering temperature was observed for A=Sr. Taken with these previous results the current work demonstrates the critical role of the A-site cation in the broadening of the π∗ bandwidth and ultimately the magnetic ordering temperature.©2017 American Physical Societyen_AU
dc.identifier.articlenumber054430en_AU
dc.identifier.citationReynolds, E., Avdeev, M., Thorogood, G. J., Poineau, F., Czerwinski, K. R., Kimpton, J. A., Yu, M., Kayser, P., & Kennedy, B. J. (2017). Structure and magnetism in Sr A_xTcO 3 perovskites: importance of the A-site cation. Physical Review B, 95(5), 054430. doi:10.1103/PhysRevB.95.054430en_AU
dc.identifier.issn2469-9969en_AU
dc.identifier.issue5en_AU
dc.identifier.journaltitlePhysical Review Ben_AU
dc.identifier.urihttps://doi.org/10.1103/PhysRevB.95.054430en_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/11041en_AU
dc.identifier.volume95en_AU
dc.language.isoenen_AU
dc.publisherAmerican Physical Societyen_AU
dc.subjectPhase transformationsen_AU
dc.subjectAntiferromagnetismen_AU
dc.subjectMagnetic propertiesen_AU
dc.subjectX-ray diffractionen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectNeel temperatureen_AU
dc.subjectCationsen_AU
dc.titleStructure and magnetism in Sr A_xTcO 3 perovskites: importance of the A-site cationen_AU
dc.typeJournal Articleen_AU
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