The novel stairs-like layered compound Co5(OH)6(H2O)2[SO3]2

Ben Yahia, H; Shikano, M; Avdeev, M; Belharouak, I

The novel stairs-like layered compound Co5(OH)6(H2O)2[SO3]2

Date

2017-02-15

Authors

Publisher

De Gruyter

Abstract

The new compound Co5(OH)6(H2O)2[SO3]2 was synthesized by a hydrothermal route and its crystal structure was determined from the combination of sin-gle crystal X-ray- and neutron powder-diffraction data. Co5(OH)6(H2O)2[SO3]2 crystallizes with the space group P21/c, a= 7.0229(19) Å, b= 5.4722(15) Å, c= 15.833(4), β= 106.34(1)°, V= 583.9(3) Å3 and Z= 4. The crystal struc-ture consists of a 2D-framework of cobalt octahedra shar-ing corners and edges and giving rise to a stairs-like layers, interconnected through O–H···O–S4 + hydrogen bonds. © Walter de Gruyter GmbH 2021

Keywords

Crystal structure, Hydrothermal systems, X-ray diffraction, Neutron diffraction, Cobalt, Layers, Monocrystals

Citation

Ben Yahia, H., Shikano, M., Avdeev, M., & Belharouak, I. (2017). The novel stairs-like layered compound Co5(OH)6(H2O)2[SO3]2. Zeitschrift für Kristallographie - Crystalline Materials, 232(5), 349-355. doi:10.1515/zkri-2016-2019