Pu, U, and Hf incorporation in Gd silicate apatite

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dc.contributor.authorVance, ERen_AU
dc.contributor.authorBall, CJen_AU
dc.contributor.authorBegg, BDen_AU
dc.contributor.authorCarter, MLen_AU
dc.contributor.authorDay, RAen_AU
dc.contributor.authorThorogood, GJen_AU
dc.date.accessioned2022-04-21T07:38:34Zen_AU
dc.date.available2022-04-21T07:38:34Zen_AU
dc.date.issued2004-12-20en_AU
dc.date.statistics2022-04-07en_AU
dc.description.abstractTrivalent Pu can be incorporated in the silicate apatite structure to form Ca2Pu8(SiO4)6O2 by sintering under reducing conditions, while the incorporation of tetravalent Pu in the Ca/rare earth sites in oxidizing or neutral conditions is limited to only 0.6 formula units (f.u.). The d-spacings and intensities of the X-ray pattern of hexagonally structured Ca2Pu8(SiO4)6O2 after firing at 1250°C are given, and the a and c lattice parameters are 0.95611 and 0.70281 nm, respectively. The respective solid solubility limits of U and Hf in Ca2Gd8–x(U/Hf)x(SiO4)6O2 apatite samples were 0.3 and 0.2 f.u. © 2004 The American Ceramic Societyen_AU
dc.identifier.citationVance, E. R., Ball, C. J., Begg, B. D., Carter, M. L., Day, R. A., & Thorogood, G. J. (2003). Pu, U, and Hf incorporation in Gd silicate apatite. Journal of the American Ceramic Society, 86(7), 1223-1225. doi:10.1111/j.1151-2916.2003.tb03455.xen_AU
dc.identifier.issn1551-2916en_AU
dc.identifier.issue7en_AU
dc.identifier.journaltitleJournal of the American Ceramic Societyen_AU
dc.identifier.pagination1223-1225en_AU
dc.identifier.urihttps://doi.org/10.1111/j.1151-2916.2003.tb03455.xen_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/13061en_AU
dc.identifier.volume86en_AU
dc.language.isoenen_AU
dc.publisherJohn Wiley & Sons, Incen_AU
dc.subjectApatitesen_AU
dc.subjectSilicatesen_AU
dc.subjectUraniumen_AU
dc.subjectUranium compoundsen_AU
dc.subjectPlutoniumen_AU
dc.subjectHafniumen_AU
dc.subjectHafnium compoundsen_AU
dc.titlePu, U, and Hf incorporation in Gd silicate apatiteen_AU
dc.typeJournal Articleen_AU
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