Structures in the system CaTiO3/SrTiO3

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Date
1998-09
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier
Abstract
At room temperature the sequence of phases with increasing amounts of strontium in the system CaTiO3/SrTiO3is orthorhombic (Pnma), orthorhombic (Bmmb), tetragonal (I4/mcm), and cubic (Pm3m). All phase boundaries shift toward smaller strontium contents with increase of temperature. Volume changes resulting from phase transformations are small for all compositions. Shape changes are greatest (∼0.3%) for theBmmb/I4/mcmtransition, but would probably be accommodated by microtwinning and so are unlikely to affect the mechanical integrity of a specimen. ©1998 Academic Press
Description
Keywords
Microstructure, Titanium, Calcium, Strontium, Oxides, Phase transformations, Twinning
Citation
Ball, C. J., Begg, B. D., Cookson, D. J., Thorogood, G. J., & Vance, E. R. (1998). Structures in the system CaTiO3/SrTiO3. Journal of Solid State Chemistry, 139(2), 238-247. doi:10.1006/jssc.1998.7836
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