The influence of composition and temperature on the phases in Sr1−xBaxZrO3 perovskites: a high-resolution powder diffraction study
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Date
2001-10
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Elsevier
Abstract
High-resolution synchrotron X-ray diffraction measurements on a series of polycrystalline samples of Sr1−xBaxZrO3 at room temperature show that the symmetry increases with increasing Ba content, the sequence of phases being orthorhombic Pnma, orthorhombic Imma, tetragonal I4/mcm, and cubic Pmm. The effect of temperature has also been studied for a number of compositions and indicates that the same series of phases is present. The transition temperatures decrease with increasing Ba content. © 2001 Academic Press
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Keywords
Phase shift, Perovskites, X-ray diffraction, Synchrotrons, Polycrystals, Transition temperature
Citation
Kennedy, B. J., Howard, C. J., Thorogood, G. J., & Hester, J. R. (2001). The influence of composition and temperature on the phases in Sr1− xBaxZrO3 perovskites: a high-resolution powder diffraction study. Journal of Solid State Chemistry, 161(1), 106-112. doi:10.1006/jssc.2001.9295