A large spin-crossover [Fe4L4]8+ tetrahedral cage

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dc.contributor.authorLi, Len_AU
dc.contributor.authorSaigo, Nen_AU
dc.contributor.authorZhang, YJen_AU
dc.contributor.authorFanna, DJen_AU
dc.contributor.authorShepherd, NDen_AU
dc.contributor.authorClegg, JKen_AU
dc.contributor.authorZheng, RKen_AU
dc.contributor.authorHayami, Sen_AU
dc.contributor.authorLindoy, LFen_AU
dc.contributor.authorAldrich-Wright, JRen_AU
dc.contributor.authorLi, CGen_AU
dc.contributor.authorReynolds, JKen_AU
dc.contributor.authorHarman, DGen_AU
dc.contributor.authorLi, Fen_AU
dc.date.accessioned2020-03-25T02:30:31Zen_AU
dc.date.available2020-03-25T02:30:31Zen_AU
dc.date.issued2015-05-20en_AU
dc.date.statistics2020-03-20en_AU
dc.description.abstractA large discrete face-capped tetranuclear iron(II) cage, [Fe4L4](BF4)8·n(solvent), was synthesised via metal-ion directed self-assembly. The cage is formed from a rigid tritopic ligand that incorporates chelating imidazole-imine functional groups. The cage displays temperature induced spin-crossover and LIESST effects and is amongst the largest iron(II) tetrahedral cages with such properties reported. The synthesis, structure and magnetic properties of this new metallo-cage are presented. © 2015 The Royal Society of Chemistryen_AU
dc.identifier.citationLi, L., Saigo, N., Zhang, Y., Fanna, D. J., Shepherd, N. D., Clegg, J. K., Zheng, R., Hayami, S., Lindoy, L. F., Aldrich-Wright, J. R., Li, C. G., Reynolds, J. S., Harman, D. G. & Li, F. (2015). A large spin-crossover [Fe 4 L 4] 8+ tetrahedral cage. Journal of Materials Chemistry C, 3(30), 7878-7882. doi:10.1039/C5TC00991Jen_AU
dc.identifier.govdoc9077en_AU
dc.identifier.issn2050-7526en_AU
dc.identifier.issue30en_AU
dc.identifier.journaltitleJournal of Materials Chemistry Cen_AU
dc.identifier.pagination7878-7882en_AU
dc.identifier.urihttps://doi.org/10.1039/C5TC00991Jen_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/9233en_AU
dc.identifier.volume3en_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectSpin glass stateen_AU
dc.subjectAmbient temperatureen_AU
dc.subjectLigandsen_AU
dc.subjectMethanolen_AU
dc.subjectCrystalsen_AU
dc.subjectElectron microscopyen_AU
dc.titleA large spin-crossover [Fe4L4]8+ tetrahedral cageen_AU
dc.typeJournal Articleen_AU
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