Mössbauer study of the temperature dependence of electron delocalization in mixed valence freudenbergite

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dc.contributor.authorCashion, JDen_AU
dc.contributor.authorVance, ERen_AU
dc.contributor.authorRyan, DHen_AU
dc.date.accessioned2020-09-02T23:21:13Zen_AU
dc.date.available2020-09-02T23:21:13Zen_AU
dc.date.issued2020-05-04en_AU
dc.date.statistics2020-09-01en_AU
dc.description.abstractThe evolution of the electron delocalization in the ferrous subspectra in a sample of mixed valence ferrous‐ferric freudenbergite has been followed by Mössbauer spectroscopy from 6 K to 650 K. The spectral changes do not involve the ferric component, leading to the conclusion that it is due to a thermally driven delocalization of the sixth d‐electron on the ferrous ions. The phenomenon does not occur in samples of pure ferrous freudenbergite. © 1999-2020 John Wiley & Sons, Inc.en_AU
dc.identifier.citationCashion, J. D., Vance, E. R., & Ryan, D. H. (2020). Mössbauer study of the temperature dependence of electron delocalization in mixed valence freudenbergite. Journal of the American Ceramic Society, 103(10), 5496-5501. doi:10.1111/jace.17190en_AU
dc.identifier.govdoc9990en_AU
dc.identifier.issn0002-7820en_AU
dc.identifier.issue10en_AU
dc.identifier.journaltitleJournal of the American Ceramic Societyen_AU
dc.identifier.pagination5496-5501en_AU
dc.identifier.urihttps://doi.org/10.1111/jace.17190en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/9762en_AU
dc.identifier.volume103en_AU
dc.language.isoenen_AU
dc.publisherJohn Wiley & Sons, Inc.en_AU
dc.subjectTemperature dependenceen_AU
dc.subjectSpectroscopyen_AU
dc.subjectElectronsen_AU
dc.subjectIron compoundsen_AU
dc.subjectTemperature rangeen_AU
dc.subjectSpectraen_AU
dc.titleMössbauer study of the temperature dependence of electron delocalization in mixed valence freudenbergiteen_AU
dc.typeJournal Articleen_AU
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