Studying the effects of Zr-doping in (Bi0.5Na0.5)TiO3 via diffraction and spectroscopy

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dc.contributor.authorBlanchard, PERen_AU
dc.contributor.authorLiu, Sen_AU
dc.contributor.authorKennedy, BJen_AU
dc.contributor.authorLing, CDen_AU
dc.contributor.authorZhang, Zen_AU
dc.contributor.authorAvdeev, Men_AU
dc.contributor.authorJang, LYen_AU
dc.contributor.authorLee, JFen_AU
dc.contributor.authorPao, CWen_AU
dc.contributor.authorChen, JLen_AU
dc.date.accessioned2016-06-20T00:42:10Zen_AU
dc.date.available2016-06-20T00:42:10Zen_AU
dc.date.issued2014-10-13en_AU
dc.date.statistics2016-06-20en_AU
dc.description.abstractThe structural properties of (Bi0.5Na0.5)Ti1−xZrxO3 (where 0 ≤ x ≤ 0.7) have been investigated using powder diffraction and X-ray absorption spectroscopy. Diffraction measurements on (Bi0.5Na0.5)TiO3 confirm that both monoclinic Cc and rhombohedral R3c phases are present at room temperature. Doping small amounts of Zr into the B site of (Bi0.5Na0.5)TiO3 initially stabilizes the rhombohedral phase before the orthorhombic Pnma phase begins to form at x = 0.5. Analysis of the Ti K-edge and Zr L3-edge XANES spectra show that the crystallographic phase change has very little effect on the local structure of Ti4+/Zr4+ cations, suggesting that there is little change in the cation off-center displacement within the BO6 octahedra with each successive phase change. © The Royal Society of Chemistry 2014en_AU
dc.identifier.citationBlanchard, P. E. R., Liu, S., Kennedy, B. J., Ling, C. D., Zhang, Z., Avdeev, M., Jang. L. Y., Lee, J. F., Pao, C. W., & Chen, J. L. (2014). Studying the effects of Zr-doping in (Bi0.5Na0.5)TiO3via diffraction and spectroscopy. Dalton Transactions, 43(46), 17358-17365. doi:10.1039/c4dt02520ben_AU
dc.identifier.govdoc6721en_AU
dc.identifier.issn1477-9234en_AU
dc.identifier.issue46en_AU
dc.identifier.journaltitleDalton Transactionsen_AU
dc.identifier.pagination17358-17365en_AU
dc.identifier.urihttp://dx.doi.org/10.1039/C4DT02520Ben_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/7039en_AU
dc.identifier.volume43en_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectBuilding materialsen_AU
dc.subjectX-ray spectroscopyen_AU
dc.subjectDiffractionen_AU
dc.subjectAbsorptionen_AU
dc.subjectTrigonal latticesen_AU
dc.subjectCationsen_AU
dc.titleStudying the effects of Zr-doping in (Bi0.5Na0.5)TiO3 via diffraction and spectroscopyen_AU
dc.typeJournal Articleen_AU
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