Spectroscopic studies and crystal structures of double thorium(IV) oxalates with sodium ions

Simple item page
dc.contributor.authorZhang, YJen_AU
dc.contributor.authorBhadbhade, MMen_AU
dc.contributor.authorKaratchevtseva, Ien_AU
dc.contributor.authorGao, Jen_AU
dc.contributor.authorPrice, JRen_AU
dc.contributor.authorLumpkin, GRen_AU
dc.date.accessioned2015-11-01T03:01:55Zen_AU
dc.date.available2015-11-01T03:01:55Zen_AU
dc.date.issued2013-11-08en_AU
dc.date.statistics2015-10-28en_AU
dc.description.abstractTwo new double thorium oxalates with sodium ions have been prepared and characterized by using scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDS), Raman spectroscopy and single-crystal X-ray diffraction. The crystal structure of Na4[Th(C2O4)4]·5.5H2O (1) contains infinite chains, [Th(μ2-C2O4)2(C2O4)3]n4n–, with three terminating bidentate and two bridging tetradentate oxalate ligands. The crystal structure of Na10[Th2(C2O4)9]·15H2O (2) comprises unique dimers, [Th2(μ2-C2O4)(C2O4)8]10–, with Th atoms being coordinated by five oxalato ligands, four terminating bidentate and one bridging tetradentate. The structure is the first dimer of tetravalent actinide oxalato complexes. The spectroscopic results are in good agreement with the crystal structures. © 2013, Wiley-Vch Verlag.en_AU
dc.identifier.citationZhang, Y., Bhadbhade, M., Karatchevtseva, I., Gao, J., Price, J. R., & Lumpkin, G. R. (2013). Spectroscopic studies and crystal structures of double rhorium(IV) oxalates with sodium ions. European Journal of Inorganic Chemistry, 2013(36), 6170-6174. doi:10.1002/ejic.201301099en_AU
dc.identifier.govdoc6235en_AU
dc.identifier.issn1434-1948en_AU
dc.identifier.journaltitleEuropean Journal of Inorganic Chemistryen_AU
dc.identifier.pagination6170-6174en_AU
dc.identifier.urihttp://dx.doi.org/10.1002/ejic.201301099en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/6385en_AU
dc.identifier.volume2013en_AU
dc.identifier.volume36en_AU
dc.language.isoenen_AU
dc.publisherJohn Wiley and Sonsen_AU
dc.subjectSodium ionsen_AU
dc.subjectScanning electron microscopyen_AU
dc.subjectRaman spectroscopyen_AU
dc.subjectX-ray diffractionen_AU
dc.subjectCrystal structureen_AU
dc.subjectElectron microscopyen_AU
dc.titleSpectroscopic studies and crystal structures of double thorium(IV) oxalates with sodium ionsen_AU
dc.typeJournal Articleen_AU
Files
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Journal Articles