High-yield synthesis and crystal structure of a green Au30 cluster co-capped by thiolate and sulfide
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Date
2016-09-24
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Publisher
Royal Society of Chemistry
Abstract
A green gold-cluster, Au30S(StBu)18, was successfully prepared in high yield and crystallographically characterized. Each cluster consists of an Au22 core capped by a mixed layer of staple Au-thiolate units, bridging thiolates and a μ3-S2−.© 2014, The Royal Society of Chemistry.
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Keywords
Crystallography, Metals, Cluster model, Layers, Data, Yields
Citation
Yang, H., Wang, Y., Edwards, A. J., Yan, J., & Zheng, N. (2014). High-yield synthesis and crystal structure of a green Au30 cluster co-capped by thiolate and sulfide. [10.1039/C4CC01773K]. Chemical Communications, 50(92), 14325-14327. doi:10.1039/c4cc01773k