Synthesis, structure and gas-phase reactivity of a silver hydride complex ag-3{(PPh2)(2)CH2}(3)(mu(3)-H)(mu(3)-Cl) BF4

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dc.contributor.authorZavras, Aen_AU
dc.contributor.authorKhairallah, GNen_AU
dc.contributor.authorConnell, TUen_AU
dc.contributor.authorWhite, JMen_AU
dc.contributor.authorEdwards, AJen_AU
dc.contributor.authorDonnelly, PSen_AU
dc.contributor.authorO'Hair, RAJen_AU
dc.date.accessioned2015-11-01T02:59:16Zen_AU
dc.date.available2015-11-01T02:59:16Zen_AU
dc.date.issued2013-08-05en_AU
dc.date.statistics2015-10-28en_AU
dc.description.abstractMass spectrometry shows the way! MS analysis of silver salts treated with sodium borohydride in the presence of a bis(phosphino) ligand revealed the formation of novel silver hydride nanocluster cations instead of all silver nanocluster cations. This serendipitous discovery prompted the condensed-phase synthesis, isolation, and characterization of [Ag3{(Ph2P)2CH2}3(μ3-H)(μ3-Cl)]BF4⋅0.5 CHCl3. © 2013, Wiley‐Vch Verlag.en_AU
dc.identifier.citationZavras, A., Khairallah, G. N., Connell, T. U., White, J. M., Edwards, A. J., Donnelly, P. S., & O'Hair, R. A. J. (2013). Synthesis, structure and gas-phase reactivity of a silver hydride complex Ag-3{(PPh2)(2)CH2}(3)(mu(3)-H)(mu(3)-Cl) BF4. Angewandte Chemie International Edition, 52(32), 8391-8394. doi:10.1002/anie.201302436en_AU
dc.identifier.govdoc6234en_AU
dc.identifier.issn1433-7851en_AU
dc.identifier.issue32en_AU
dc.identifier.journaltitleAngewandte Chemie International Editionen_AU
dc.identifier.pagination8391-8394en_AU
dc.identifier.urihttp://dx.doi.org/10.1002/anie.201302436en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/6384en_AU
dc.identifier.volume52en_AU
dc.language.isoenen_AU
dc.publisherJohn Wiley and Sonsen_AU
dc.subjectMass spectroscopyen_AU
dc.subjectLigandsen_AU
dc.subjectCatalystsen_AU
dc.subjectAlkynesen_AU
dc.subjectGold compoundsen_AU
dc.subjectCrystallizationen_AU
dc.titleSynthesis, structure and gas-phase reactivity of a silver hydride complex ag-3{(PPh2)(2)CH2}(3)(mu(3)-H)(mu(3)-Cl) BF4en_AU
dc.typeJournal Articleen_AU
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