Proton cascade in a molecular solid: H/D exchange on mobile and immobile water
No Thumbnail Available
Date
2013-12-09
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley
Abstract
Working without pores: In non-porous, channel-free crystals of a manganese citrate coordination polymer, neutron diffraction reveals that the water molecules, both metal-bound and co-crystallized, undergo full hydrogen/deuterium exchange. Neutron diffraction analyses show a pattern of hydrogen disorder that can be interpreted in terms of the Grotthuss proton-cascade mechanism. © 1999-2020 John Wiley & Sons, Inc.
Description
Keywords
Chemistry, Hydrogen, Hydrogen transfer, Neutron diffraction, X-ray diffraction, Neutrons
Citation
Capelli, S.C., Falvello, L. R., Forcén-Vázquez, E., McIntyre, G. J., Palacio, F., Sanz. S., & Tomás, M. (2013). Proton cascade in a molecular solid: H/D exchange on mobile and immobile water. Angewandte Chemie International Edition, 52(50), 13463-13467. doi:10.1002/anie.201307994