Ultramicroporous MOF with high concentration of vacant Cu 11 sites

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dc.contributor.authorMcCormick, LJen_AU
dc.contributor.authorDuyker, SGen_AU
dc.contributor.authorThornton, AWen_AU
dc.contributor.authorHawes, CSen_AU
dc.contributor.authorHill, MRen_AU
dc.contributor.authorPeterson, VKen_AU
dc.contributor.authorBatten, SRen_AU
dc.contributor.authorTurner, DRen_AU
dc.date.accessioned2016-09-30T01:46:38Zen_AU
dc.date.available2016-09-30T01:46:38Zen_AU
dc.date.issued2015-07en_AU
dc.date.statistics2016-09-30en_AU
dc.description.abstractAn ultramicroporous metal–organic framework (MOF) is reported that contains 0.35 nm nanotube-like channels with an unprecedented concentration of vacant CuII coordination sites. The nonintersecting, narrow channels in [Cu3(cdm)4] (cdm = C(CN)2(CONH2)−) align in two perpendicular directions, structurally resembling copper-doped carbon nanotubes with CuII embedded in the walls of the channels. The combination of ultramicroporosity with the exposed CuII coordination sites gives size-based selectivity of CO2 over CH4, based on pore-size distribution and modeling. Neutron powder diffraction and molecular dynamics simulations show the close packing of single rows of guests within the tubular nanostructure and interaction of CO2 with the exposed metal sites. © 2014, American Chemical Society.en_AU
dc.identifier.citationMcCormick, L. J., Duyker, S. G., Thornton, A. W., Hawes, C. S., Hill, M. R., Peterson, V. K., Batten, S. R., & Turner, D. R. (2014). Ultramicroporous MOF with high concentration of vacant Cu 11 sites. Chemistry of Materials, 26(15), 4640-4646. doi:10.1021/cm502189cen_AU
dc.identifier.govdoc7205en_AU
dc.identifier.issn1520-5002en_AU
dc.identifier.issue15en_AU
dc.identifier.journaltitleChemistry of Materialsen_AU
dc.identifier.pagination4640-4646en_AU
dc.identifier.urihttp://dx.doi.org/10.1021/cm502189cen_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/7622en_AU
dc.identifier.volume26en_AU
dc.language.isoenen_AU
dc.publisherAmerican Chemical Societyen_AU
dc.subjectMetalsen_AU
dc.subjectNanotubesen_AU
dc.subjectCarbonen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectCopperen_AU
dc.subjectNanostructuresen_AU
dc.titleUltramicroporous MOF with high concentration of vacant Cu 11 sitesen_AU
dc.typeJournal Articleen_AU
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