Surface segregation of niobium and tantalum in titanium dioxide. Overview

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dc.contributor.authorAtanacio, AJen_AU
dc.contributor.authorIkuma, Yen_AU
dc.date.accessioned2016-06-07T00:37:00Zen_AU
dc.date.available2016-06-07T00:37:00Zen_AU
dc.date.issued2016-02-15en_AU
dc.date.statistics2016-06-07en_AU
dc.description.abstractSegregation in crystals results in surface layer enrichment of selected lattice elements. The present work considers the phenomenon of segregation in solid solutions of TiO2 doped with donor-type elements, such as niobium and tantalum. The focus is on the effect of oxygen activity on segregation at elevated temperatures. It is shown that the effect of oxygen activity on the segregation-induced enrichment may be used for engineering of oxide materials in general and TiO2-based materials in particular with controlled surface composition that is required to achieve the desired reactivity and photoreactivity for energy conversion in general and solar energy conversion in particular. The development of the related surface engineering procedures requires correct determination of oxygen activity during processing and the segregation-induced concentration gradients within the surface layer.© The American Ceramic Society, 2016.Copyright © 1999-2020 John Wiley & Sons, Incen_AU
dc.identifier.citationAtanacio, A. J., & Ikuma, Y. (2016). Surface segregation of niobium and tantalum in titanium dioxide. Overview. Journal of the American Ceramic Society, 99(5), 1512-1519. doi: 10.1111/jace.14122en_AU
dc.identifier.govdoc6645en_AU
dc.identifier.issn1551-2916en_AU
dc.identifier.issue5en_AU
dc.identifier.journaltitleJournal of the American Ceramic Societyen_AU
dc.identifier.pagination1512-1519en_AU
dc.identifier.urihttp://www.doi.org/10.1111/jace.14122en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/6919en_AU
dc.identifier.volume99en_AU
dc.language.isoenen_AU
dc.publisherJohn Wiley & Sonsen_AU
dc.subjectSegregationen_AU
dc.subjectNiobiumen_AU
dc.subjectTantalumen_AU
dc.subjectTitaniumen_AU
dc.subjectOxygenen_AU
dc.subjectReactivityen_AU
dc.titleSurface segregation of niobium and tantalum in titanium dioxide. Overviewen_AU
dc.typeJournal Articleen_AU
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