Structural and magnetic studies of Zn doped LaRh(1-2x)Cu2xO3

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dc.contributor.authorAwin, LAen_AU
dc.contributor.authorKennedy, BJen_AU
dc.contributor.authorAvdeev, Men_AU
dc.date.accessioned2015-01-27T23:20:38Zen_AU
dc.date.available2015-01-27T23:20:38Zen_AU
dc.date.issued2013-04-10en_AU
dc.date.statistics2015-01-28en_AU
dc.description.abstractTwo series of Zn doped Rh perovskites LaRh1-2xCux ZnxO3 and La0.75Pb0.25Rh1-2xCuxZnxO3 (0≤ x ≤0.25) were synthesised by solid-state methods and their crystallographic, magnetic, and electric properties investigated. Both series have an orthorhombic perovskite-type structure in space group Pbnm. The increase in Zn content has an obvious impact on the electron delocalisation in which the shift in the average valency of Cu and Rh (+2.5 and +3.5) has resulted in a reduction in cell volumes and an increase in the effective magnetic moments. The Curie–Weiss magnetization curves measured between 5-300K are indicative of antiferromagnetism. The addition of Pb to the A- site decreases the conductivity as anticipated. © 2013 Trans Tech Publicationsen_AU
dc.identifier.citationAwin, L.A., Kennedy, B.J., & Avdeev, M. (2013). Structural and magnetic studies of Zn doped LaRh(1-2x)Cu2xO3. Key Engineering Materials, 547, 173-180. doi:10.4028/www.scientific.net/KEM.547.173en_AU
dc.identifier.govdoc5391en_AU
dc.identifier.issn1662-9795en_AU
dc.identifier.journaltitleKey Engineering Materialsen_AU
dc.identifier.pagination173-180en_AU
dc.identifier.urihttp://dx.doi.org/10.4028/www.scientific.net/KEM.547.173en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/6118en_AU
dc.identifier.volume547en_AU
dc.language.isoenen_AU
dc.publisherTrans Tech Publicationsen_AU
dc.subjectLeaden_AU
dc.subjectMagnetizationen_AU
dc.subjectPerovskiteen_AU
dc.subjectLanthanumen_AU
dc.subjectRhodiumen_AU
dc.subjectCopperen_AU
dc.titleStructural and magnetic studies of Zn doped LaRh(1-2x)Cu2xO3en_AU
dc.typeJournal Articleen_AU
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