Single crystal and magnetic structures of maricite-type AgMnVO4
dc.contributor.author | Ben Yahia, H | en_AU |
dc.contributor.author | Shikano, M | en_AU |
dc.contributor.author | Gaudin, E | en_AU |
dc.contributor.author | Avdeev, M | en_AU |
dc.contributor.author | Ling, CD | en_AU |
dc.date.accessioned | 2017-05-09T01:38:41Z | en_AU |
dc.date.available | 2017-05-09T01:38:41Z | en_AU |
dc.date.issued | 2015-01 | en_AU |
dc.date.statistics | 2017-05-09 | en_AU |
dc.description.abstract | Single crystals of the ternary manganese vanadate AgMnVO4, were grown using AgVO3 flux. The structure was determined from single crystal X-ray diffraction data. The magnetic structure and properties of AgMnVO4 were characterized by magnetic susceptibility, specific heat, and low-temperature neutron powder diffraction measurements. AgMnVO4 crystallizes in the maricite-type structure with space group Pnma, a=9.5393(12), b=6.8132(9), c=5.3315(7) Å and Z=4. AgMnVO4 contains MnO4 chains made up of edge-sharing MnO6 octahedra, and these chains are interlinked by the VO4 and AgO4 tetrahedra. The specific heat measurements indicate a 3D-antiferromagnetic ordering at ~12.1 K and the neutron powder diffraction measurements at 5 K show that the Mn2+magnetic moments are antiferromagnetically coupled within the chains which are antiferromagnetically coupled to each other. © 2014, Elsevier Inc. | en_AU |
dc.identifier.citation | Ben Yahia, H., Shikano, M., Gaudin, E., Avdeev, M., & Ling, C. D. (2015). Single crystal and magnetic structures of maricite-type AgMnVO4. Journal of Solid State Chemistry, 221, 306-310. doi:10.1016/j.jssc.2014.09.017 | en_AU |
dc.identifier.govdoc | 8164 | en_AU |
dc.identifier.issn | 0022-4596 | en_AU |
dc.identifier.journaltitle | Journal of Solid State Chemistry | en_AU |
dc.identifier.pagination | 306-310 | en_AU |
dc.identifier.uri | http://www.sciencedirect.com/science/article/pii/S0022459614004113 | en_AU |
dc.identifier.uri | http://apo.ansto.gov.au/dspace/handle/10238/8684 | en_AU |
dc.identifier.volume | 221 | en_AU |
dc.language.iso | en | en_AU |
dc.publisher | Elsevier | en_AU |
dc.subject | Crystals | en_AU |
dc.subject | X-ray diffraction | en_AU |
dc.subject | Magnetization | en_AU |
dc.subject | Antiferromagnetic materials | en_AU |
dc.subject | Chains | en_AU |
dc.subject | Manganese | en_AU |
dc.title | Single crystal and magnetic structures of maricite-type AgMnVO4 | en_AU |
dc.type | Journal Article | en_AU |
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