Lanthanoid “bottlebrush” clusters: remarkably elongated metal–oxo core structures with controllable lengths

Simple item page
dc.contributor.authorD'Alessio, Den_AU
dc.contributor.authorSobolev, ANen_AU
dc.contributor.authorSkelton, BWen_AU
dc.contributor.authorFuller, ROen_AU
dc.contributor.authorWoodward, RCen_AU
dc.contributor.authorLengkeek, NAen_AU
dc.contributor.authorFraser, BHen_AU
dc.contributor.authorMassi, Men_AU
dc.contributor.authorOgden, MIen_AU
dc.date.accessioned2020-03-12T02:53:12Zen_AU
dc.date.available2020-03-12T02:53:12Zen_AU
dc.date.issued2014-10-04en_AU
dc.date.statistics2020-03-11en_AU
dc.descriptionACS AuthorChoice - This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. Terms of use can be found here: https://pubs.acs.org/page/policy/authorchoice_termsofuse.htmlen_AU
dc.description.abstractLarge metal–oxo clusters consistently assume spherical or regular polyhedral morphologies rather than high-aspect-ratio structures. Access to elongated core structures has now been achieved by the reaction of lanthanoid salts with a tetrazole-functionalized calixarene in the presence of a simple carboxylate co-ligand. The resulting Ln19 and Ln12 clusters are constructed from apex-fused Ln5O6 trigonal bipyramids and are formed consistently under a range of reaction conditions and reagent ratios. Altering the carboxylate co-ligand structure reliably controls the cluster length, giving access to a new class of rod-like clusters of variable length. © 2014 American Chemical Societyen_AU
dc.identifier.citationD’Alessio, D., Sobolev, A. N., Skelton, B. W., Fuller, R. O., Woodward, R. C., Lengkeek, N. A., Fraser, B. H. Massi., M, & Ogden, M. I. (2014). Lanthanoid “bottlebrush” clusters: remarkably elongated metal–oxo core structures with controllable lengths. Journal of the American Chemical Society, 136(43), 15122-15125. doi:10.1021/ja506677hen_AU
dc.identifier.govdoc8703en_AU
dc.identifier.issn1520-5126en_AU
dc.identifier.issue43en_AU
dc.identifier.journaltitleJournal of the American Chemical Societyen_AU
dc.identifier.pagination15122-15125en_AU
dc.identifier.urihttp://doi.org/10.1021/ja506677hen_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/9145en_AU
dc.identifier.volume136en_AU
dc.language.isoenen_AU
dc.publisherJournal of the American Chemical Societyen_AU
dc.subjectRare earthsen_AU
dc.subjectMetalsen_AU
dc.subjectLigandsen_AU
dc.subjectChemistryen_AU
dc.subjectReagentsen_AU
dc.subjectPolymersen_AU
dc.titleLanthanoid “bottlebrush” clusters: remarkably elongated metal–oxo core structures with controllable lengthsen_AU
dc.typeJournal Articleen_AU
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
ja506677h.pdf
Size:
1.38 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Journal Articles