Dysprosium complexes with mono-/di-carboxylate ligands—from simple dimers to 2D and 3D frameworks

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dc.contributor.authorZhang, YJen_AU
dc.contributor.authorBhadbhade, MMen_AU
dc.contributor.authorScales, Nen_AU
dc.contributor.authorKaratchevtseva, Ien_AU
dc.contributor.authorPrice, JRen_AU
dc.contributor.authorLu, KTen_AU
dc.contributor.authorLumpkin, GRen_AU
dc.date.accessioned2016-11-08T05:37:17Zen_AU
dc.date.available2016-11-08T05:37:17Zen_AU
dc.date.issued2014-11-01en_AU
dc.date.statistics2016-11-07en_AU
dc.description.abstractFour dysprosium (Dy) single carboxylates, a formate, a propionate, a butyrate and an oxalate have been synthesized and structurally characterized. The structure of Dy(HCO2)3 (1) contains nine-fold coordinated Dy polyhedra in perfect tricapped trigonal prisms. They are linked through trigonal O atoms forming 1D pillars which are further linked together through tricapped O atoms into a 3D pillared metal organic framework. The network structure is stable up to 360 °C. The structure of [Dy2(C2O4)3(H2O)6]·2.5H2O (2) contains nine-fold coordinated Dy polyhedra linking together through μ2-bridging oxalate anions into a 2D hexagonal layered structure. Both [Dy2(Pr)6(H2O)4]·(HPr)0.5 (3) [Pr=(C2H5CO2)−1] and [Dy2(Bu)6(H2O)4] (4) [Bu=(C3H7CO2)−1] have similar di-nuclear structures. The Raman vibration modes of the complexes have been investigated. © 2016 Elsevier B.V.en_AU
dc.identifier.citationZhang, Y., Bhadbhade, M., Scales, N., Karatchevtseva, I., Price, J. R., Lu, K., & Lumpkin, G. R. (2014). Dysprosium complexes with mono-/di-carboxylate ligands—from simple dimers to 2D and 3D frameworks. Journal of Solid State Chemistry, 219, 1-8. doi:10.1016/j.jssc.2014.07.007en_AU
dc.identifier.govdoc7582en_AU
dc.identifier.issn0022-4596en_AU
dc.identifier.journaltitleJournal of Solid State Chemistryen_AU
dc.identifier.pagination1-8en_AU
dc.identifier.urihttp://dx.doi.org/10.1016/j.jssc.2014.07.007en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/8040en_AU
dc.identifier.volume219en_AU
dc.language.isoenen_AU
dc.publisherElsevieren_AU
dc.subjectDysprosiumen_AU
dc.subjectFormatesen_AU
dc.subjectOxalatesen_AU
dc.subjectLigandsen_AU
dc.subjectCarboxylic acidsen_AU
dc.subjectRare earthsen_AU
dc.titleDysprosium complexes with mono-/di-carboxylate ligands—from simple dimers to 2D and 3D frameworksen_AU
dc.typeJournal Articleen_AU
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