Synthesis, structures and properties of transition metal doped SrIrO3

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dc.contributor.authorQasim, Ien_AU
dc.contributor.authorKennedy, BJen_AU
dc.contributor.authorAvdeev, Men_AU
dc.date.accessioned2013-03-12T00:17:28Zen_AU
dc.date.available2013-03-12T00:17:28Zen_AU
dc.date.issued2013-01-10en_AU
dc.date.statistics2013-03-12en_AU
dc.description.abstractThe synthesis of some transition metal SrIr1-xMxO3 type oxides is described. These have an orthorhombic perovskite type-structure and are only found when the formal oxidation state of the Ir is approximately equal to +4.5 and for M = Fe, Co, Ni and Zn. Occupancy of the TM eg type orbitals appears to contribute to the break-down of the dimeric motif seen in the 6H-SrIrO3 structure. Variable temperature resistivity measurements show that SrIr0.8Zn0.2O3 is a metal; SrIr0.8Ni0.2O3 an non-metal and SrIr0.8Co0.2O3 undergoes a temperature dependent metal-insulator transition. © 2013, Royal Society of Chemistryen_AU
dc.identifier.citationQasim, I., Kennedy, B. J., & Avdeev, M. (2013). Synthesis, structures and properties of transition metal doped SrIrO3. Journal of Materials Chemistry A, 1(9), 3127-3132. doi:10.1039/C3TA00540Ben_AU
dc.identifier.govdoc4897en_AU
dc.identifier.issn2050-7488en_AU
dc.identifier.issue9en_AU
dc.identifier.journaltitleJournal of Materials Chemistry Aen_AU
dc.identifier.pagination3127-3132en_AU
dc.identifier.urihttp://dx.doi.org/10.1039/C3TA00540Ben_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/4515en_AU
dc.identifier.volume1en_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectOxidesen_AU
dc.subjectPowdersen_AU
dc.subjectPerovskitesen_AU
dc.subjectIronen_AU
dc.subjectCobalten_AU
dc.subjectNickelen_AU
dc.titleSynthesis, structures and properties of transition metal doped SrIrO3en_AU
dc.typeJournal Articleen_AU
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