Negative thermal expansion in the metal-organic framework material Cu-3(1,3,5-benzenetricarboxylate)(2)

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dc.contributor.authorWu, Yen_AU
dc.contributor.authorKobayashi, Aen_AU
dc.contributor.authorHalder, GJen_AU
dc.contributor.authorPeterson, VKen_AU
dc.contributor.authorChapman, KWen_AU
dc.contributor.authorLock, Nen_AU
dc.contributor.authorSouthon, PDen_AU
dc.contributor.authorKepert, CJen_AU
dc.date.accessioned2009-08-25T02:23:24Zen_AU
dc.date.accessioned2010-04-30T05:06:16Zen_AU
dc.date.available2009-08-25T02:23:24Zen_AU
dc.date.available2010-04-30T05:06:16Zen_AU
dc.date.issued2008-08-08en_AU
dc.date.statistics2008-08-08en_AU
dc.description.abstractThe metal–organic framework [Cu3(btc)2] displays negative thermal expansion (NTE) over a broad temperature range. This property arises from two coincident mechanisms, each of which are unique for NTE systems: the concerted transverse vibration of triangular organic linkers, and the local dynamic distortion of dinuclear metal centers within the framework lattice. © 2008, Wiley-VCH Verlag Berlinen_AU
dc.identifier.citationWu, Y., Kobayashi, A., Halder, G. J., Peterson, V. K., Chapman, K. W., Lock, N., et al. (2008). Negative thermal expansion in the metal-organic framework material Cu-3(1,3,5-benzenetricarboxylate)(2). Angewandte Chemie International Edition, 47(46), 8929-8932. doi:10.1002/anie.200803925en_AU
dc.identifier.govdoc1402en_AU
dc.identifier.issn1433-7851en_AU
dc.identifier.issue46en_AU
dc.identifier.journaltitleAngewandte Chemie International Editionen_AU
dc.identifier.pagination8929-8932en_AU
dc.identifier.urihttp://dx.doi.org/10.1002/anie.200803925en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/1729en_AU
dc.identifier.volume47en_AU
dc.language.isoenen_AU
dc.publisherWiley-VCH Verlag Berlinen_AU
dc.subjectThermal expansionen_AU
dc.subjectPotassium compoundsen_AU
dc.subjectFerrocyanidesen_AU
dc.subjectPhase transformationsen_AU
dc.subjectDiffractionen_AU
dc.subjectValenceen_AU
dc.titleNegative thermal expansion in the metal-organic framework material Cu-3(1,3,5-benzenetricarboxylate)(2)en_AU
dc.typeJournal Articleen_AU
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