Using XANES to monitor the oxidation state of cobalt complexes

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dc.contributor.authorHall, MDen_AU
dc.contributor.authorUnderwood, CKen_AU
dc.contributor.authorFailes, TWen_AU
dc.contributor.authorForan, GJen_AU
dc.contributor.authorHambley, TWen_AU
dc.date.accessioned2008-04-21T03:55:53Zen_AU
dc.date.accessioned2010-04-30T05:02:44Zen_AU
dc.date.available2008-04-21T03:55:53Zen_AU
dc.date.available2010-04-30T05:02:44Zen_AU
dc.date.issued2007-02-14en_AU
dc.date.statistics2007-02en_AU
dc.description.abstractX-Ray absorption near-edge structure (XANES) spectroscopy was used to monitor the oxidation state of cobalt following treatment of Co-III complexes with reducing agents such as ascorbate and cysteine. It was established that the XANES spectra of mixtures of Co-II and Co-III complexes can be used to calculate proportions of the two oxidation states by monitoring the height of the Co K-edge. The relationships developed were used to estimate proportions of each complex in solutions of Co-III complexes treated with reducing agents. © 2007, CSIRO Publishingen_AU
dc.identifier.citationHall, M. D., Underwood, C. K., Failes, T. W., Foran, G. J., & Hambley, T. W. (2007). Using XANES to monitor the oxidation state of cobalt complexes. Australian Journal of Chemistry, 60(3), 180-183. doi:10.1071/CH06307en_AU
dc.identifier.govdoc1172en_AU
dc.identifier.issn0004-9425en_AU
dc.identifier.issue3en_AU
dc.identifier.journaltitleAustralian Journal of Chemistryen_AU
dc.identifier.pagination180en_AU
dc.identifier.urihttp://dx.doi.org/10.1071/CH06307en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/1091en_AU
dc.identifier.volume60en_AU
dc.language.isoenen_AU
dc.publisherCSIRO Publishingen_AU
dc.subjectAbsorptionen_AU
dc.subjectSaltsen_AU
dc.subjectAntimitotic drugsen_AU
dc.subjectSpectroscopyen_AU
dc.subjectOxidationen_AU
dc.subjectCysteineen_AU
dc.titleUsing XANES to monitor the oxidation state of cobalt complexesen_AU
dc.typeJournal Articleen_AU
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