Two stage magnetic ordering and spin idle behavior of the coordination polymer Co-3(OH)(2)(C4O4)(2)center dot 3H(2)O determined using neutron diffraction

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dc.contributor.authorMole, RAen_AU
dc.contributor.authorStride, JAen_AU
dc.contributor.authorHenry, PFen_AU
dc.contributor.authorHoelzel, Men_AU
dc.contributor.authorSenyshyn, Aen_AU
dc.contributor.authorAlberola, Aen_AU
dc.contributor.authorGarcia, CJGen_AU
dc.contributor.authorRaithby, PRen_AU
dc.contributor.authorWood, PTen_AU
dc.date.accessioned2011-09-15T04:41:03Zen_AU
dc.date.available2011-09-15T04:41:03Zen_AU
dc.date.issued2011-03-01en_AU
dc.date.statistics2011-03-21en_AU
dc.description.abstractWe report the magnetic structure of two of the magnetically ordered phases of Co-3(OH)(2)(C4O4)2 center dot 3H(2)O, a coordination polymer that consists of a triangular framework decorated with anisotropic Co(II) ions. The combination of neutron diffraction experiments and magnetic susceptibility data allows us to identify one phase as displaying spin idle behavior, where only a fraction of the moments order at intermediate temperatures, while at the lowest temperatures the system orders fully. This novel magnetic behavior is discussed within the framework of a simple Hamiltonian and representational analysis and rationalizes this multiphase behavior by considering the combination of frustration and anisotropy. © 2011, American Chemical Societyen_AU
dc.identifier.citationMole, R. A., Stride, J. A., Henry, P. F., Hoelzel, M., Senyshyn, A., Alberola, A., Garcia, C. J. G., Raithby, P. R., & Wood, P. T. (2011). Two stage magnetic ordering and spin idle behavior of the coordination polymer Co-3(OH)(2)(C4O4)(2)center dot 3H(2)O determined using neutron diffraction. Inorganic Chemistry, 50(6), 2246-2251. doi:10.1021/ic101897aen_AU
dc.identifier.govdoc3459en_AU
dc.identifier.issn0020-1669en_AU
dc.identifier.issue6en_AU
dc.identifier.journaltitleInorganic Chemistryen_AU
dc.identifier.pagination2246-2251en_AU
dc.identifier.urihttp://dx.doi.org/10.1021/ic101897aen_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/3738en_AU
dc.identifier.volume50en_AU
dc.language.isoenen_AU
dc.publisherAmerican Chemical Societyen_AU
dc.subjectNeutron diffractionen_AU
dc.subjectPolymersen_AU
dc.subjectMagnetic susceptibilityen_AU
dc.subjectSpinen_AU
dc.subjectHamiltoniansen_AU
dc.subjectAnisotropyen_AU
dc.titleTwo stage magnetic ordering and spin idle behavior of the coordination polymer Co-3(OH)(2)(C4O4)(2)center dot 3H(2)O determined using neutron diffractionen_AU
dc.typeJournal Articleen_AU
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