A flexible copper based microporous metal-organic framework displaying selective adsorption of hydrogen over nitrogen

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dc.contributor.authorNadeem, MAen_AU
dc.contributor.authorThornton, AWen_AU
dc.contributor.authorHill, MRen_AU
dc.contributor.authorStride, JAen_AU
dc.date.accessioned2011-08-16T05:13:43Zen_AU
dc.date.available2011-08-16T05:13:43Zen_AU
dc.date.issued2011-04-01en_AU
dc.date.statistics2011-08-16en_AU
dc.description.abstractA microporous metal-organic framework [Cu-3(ipO)(2)(pyz)(2)](n), (ipO = 2-hydroxyisophthalic acid, pyz = pyrazine) was synthesized via an in situ. ligand transformation reaction. The microporous framework displays helical arrays of ipo ligands holding the Cu atoms in 2D sheets, whilst the coordination of pyz molecules acts to arrange these sheets into a microporous 3D structure. Remarkable selective sorption behaviour (>5) for H-2 over N-2 is observed and explained with molecular dynamics simulations.© 2011, Royal Society of Chemistry.en_AU
dc.identifier.citationNadeem, M.A., Thornton, A.W., Hill, M.R., Stride, J.A. (2011). A flexible copper based microporous metal-organic framework displaying selective adsorption of hydrogen over nitrogen. Dalton Transactions, 40(13), 3398-3401. doi:10.1039/c0dt01531hen_AU
dc.identifier.govdoc3414en_AU
dc.identifier.issn1477-9226en_AU
dc.identifier.issue13en_AU
dc.identifier.journaltitleDalton Transactionsen_AU
dc.identifier.pagination3398-3401en_AU
dc.identifier.urihttp://dx.doi.org/10.1039/c0dt01531hen_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/3695en_AU
dc.identifier.volume40en_AU
dc.language.isoenen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.subjectHydrogenen_AU
dc.subjectNitrogenen_AU
dc.subjectLigandsen_AU
dc.subjectSorptionen_AU
dc.subjectMolecular dynamics methoden_AU
dc.subjectAtomsen_AU
dc.titleA flexible copper based microporous metal-organic framework displaying selective adsorption of hydrogen over nitrogenen_AU
dc.typeJournal Articleen_AU
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