4-phenoxyphenol: a porous molecular material

Simple item page
dc.contributor.authorThomas, LHen_AU
dc.contributor.authorCheung, Een_AU
dc.contributor.authorJones, AOFen_AU
dc.contributor.authorKallay, AAen_AU
dc.contributor.authorLemée-Cailleau, MHen_AU
dc.contributor.authorMcIntyre, GJen_AU
dc.contributor.authorWilson, CCen_AU
dc.date.accessioned2012-06-20T02:07:35Zen_AU
dc.date.available2012-06-20T02:07:35Zen_AU
dc.date.issued2012-04-01en_AU
dc.date.statistics2012-06-20en_AU
dc.description.abstract4-Phenoxyphenol is a simple organic molecule that crystallizes as a porous material with channels running throughout the structure. The channels are constructed by a 6-fold hydrogen bonded ring and can host solvent molecules incorporated during crystal growth, with a minimum channel diameter of 5.8-5.9 angstrom; each channel usually contains a single solvent molecule per unit cell. The hydrogen bonded ring shows surprising flexibility, being able both to breathe and to sustain its crystalline integrity even when grown with empty pores. This is particularly surprising given that the remainder of the interactions within the crystal structure are C-H center dot center dot center dot pi interactions and are weak in nature. It is also possible to grow "dry" porous 4-phenoxyphenol crystals by using a bulky solvent in the recrystallization. © 2012, American Chemical Society.en_AU
dc.identifier.citationThomas, L. H., Cheung, E., Jones, A. O. F., Kallay, A. A., Lemée-Cailleau, M.-H., McIntyre, G. J., & Wilson, C. C. (2012). 4-phenoxyphenol: a porous molecular material. Crystal Growth & Design, 12(4), 1746-1751. doi:10.1021/cg200998uen_AU
dc.identifier.govdoc4320en_AU
dc.identifier.issn1528-7483en_AU
dc.identifier.issue4en_AU
dc.identifier.journaltitleCrystal Growth & Designen_AU
dc.identifier.pagination1746-1751en_AU
dc.identifier.urihttp://dx.doi.org/10.1021/cg200998uen_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/4343en_AU
dc.identifier.volume12en_AU
dc.language.isoenen_AU
dc.publisherAmerican Chemical Societyen_AU
dc.subjectPorous materialsen_AU
dc.subjectDiffractionen_AU
dc.subjectCrystal structureen_AU
dc.subjectMoleculesen_AU
dc.subjectHydrogenen_AU
dc.subjectSolventsen_AU
dc.subjectMolecular structureen_AU
dc.title4-phenoxyphenol: a porous molecular materialen_AU
dc.typeJournal Articleen_AU
Files
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.63 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Journal Articles