Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions

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dc.contributor.authorBoyd, PDWen_AU
dc.contributor.authorEdwards, AJen_AU
dc.contributor.authorGardiner, MGen_AU
dc.contributor.authorHo, CCen_AU
dc.contributor.authorLemée-Cailleau, MHen_AU
dc.contributor.authorMcGuinness, DSen_AU
dc.contributor.authorRiapanitra, Aen_AU
dc.contributor.authorSteed, JWen_AU
dc.contributor.authorStringer, DNen_AU
dc.contributor.authorYates, BFen_AU
dc.date.accessioned2010-09-13T03:29:47Zen_AU
dc.date.available2010-09-13T03:29:47Zen_AU
dc.date.issued2010-08-23en_AU
dc.date.statistics2010-08-23en_AU
dc.description.abstractThe first palladium(I) N-heterocyclic carbene complex has been isolated in high yield by the base-assisted reduction of a palladium(II) precursor. The location of the unique terminal hydride (see picture; PdI cyan, H white, N blue) was established by neutron crystal structure determination, and the solution fluxional behavior of the complex was explored. © 2010, Wiley-VCH Verlag Berlinen_AU
dc.identifier.citationBoyd, P. D. W., Edwards, A. J., Gardiner, M. G., Ho, C. C., Lemée-Cailleau, M.-H., McGuinness, D. S., Riapanitra, A., Steed, J. W., Stringer, D. N., & Yates, B. F. (2010). Reduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions. Angewandte Chemie International Edition, 49(36), 6315-6318. doi:10.1002/anie.201003177en_AU
dc.identifier.govdoc2641en_AU
dc.identifier.issn1433-7851en_AU
dc.identifier.issue36en_AU
dc.identifier.journaltitleAngewandte Chemie International Editionen_AU
dc.identifier.pagination6315-6318en_AU
dc.identifier.urihttp://dx.doi.org/10.1002/anie.201003177en_AU
dc.identifier.urihttp://apo.ansto.gov.au/dspace/handle/10238/2505en_AU
dc.identifier.volume49en_AU
dc.language.isoenen_AU
dc.publisherWiley-VCH Verlag Berlinen_AU
dc.subjectPalladiumen_AU
dc.subjectHomogeneous catalysisen_AU
dc.subjectCouplingen_AU
dc.subjectCarbenesen_AU
dc.subjectCrystal structureen_AU
dc.subjectReductionen_AU
dc.titleReduction of a chelating bis(NHC) palladium(II) complex to [{μbis( NHC)}2Pd2H]+: a terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditionsen_AU
dc.typeJournal Articleen_AU
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