Potential - pH diagrams at temperatures above 298.16 degrees K, Part 2 - potential - pH diagrams of water for the temperature range 298.16 - 573.16 degrees K

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Date
1972-03
Journal Title
Journal ISSN
Volume Title
Publisher
Australian Atomic Energy Commission
Abstract
The Potential — pH diagrams are presented for water over the temperature range 298.16-573.16º K. The diagrams are discussed with reference to variation of the thermodynamic stability of species H20(l) , H +, 0H-, H-, H202, H0-2, H1, H2, 02, 0S and H20(g) with temperature. The diagrams demonstrate the variation of Kw and the neutral point of water with temperature. The maximum for Kw was —11.86 at 473.16º K (200ºC) with a corresponding minimum pH value of 5.93.
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Keywords
pH value, Water, Temperature monitoring, Thermodynamic properties
Citation
Lowson, R. T. (1972). Potential - pH diagrams at temperatures above 298.16 degrees K, Part 2 - potential - pH diagrams of water for the temperature range 298.16 - 573.16 degrees K. (AAEC/E219 Part 2). Lucas Heights, NSW: Australian Atomic Energy Commission.