Thermal and pressure-induced spin crossover in a cobalt (II) imide complex

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dc.contributor.authorNarayanaswamy, Sen_AU
dc.contributor.authorCowan, MGen_AU
dc.contributor.authorOlguin, Jen_AU
dc.contributor.authorTallon, JLen_AU
dc.contributor.authorBrooker, Sen_AU
dc.date.accessioned2022-08-30T05:34:18Zen_AU
dc.date.available2022-08-30T05:34:18Zen_AU
dc.date.issued2012-01-31en_AU
dc.date.statistics2021-09-07en_AU
dc.description.abstractWe report the thermal- and pressure-induced spin-crossover (SCO) in the Co(II) imide complex [CoII(dpzca)2] using magnetic susceptibility measurements and high-pressure Raman spectroscopy. This complex displays thermally-induced reversible, complete, abrupt and hysteretic SCO, with T1/2↓ = 168 K upon cooling and T1/2↑ = 179 K upon heating with a thermal hysteresis of ~11K and a pressure-induced reversible high spin (HS) ⇄ low spin (LS) transition at ~0.3 GPa at room temperature.en_AU
dc.identifier.citationNarayanaswamy, S., Cowan, M. G., Olguin, Tallon, J. L., & Brooker, S. (2012). Thermal and pressure-induced spin crossover in a cobalt (II) imide complex. Paper presented to the 36th Annual Condensed Matter and Materials Meeting, Wagga 2012, Charles Sturt University, Wagga Wagga, NSW 31st January – 3rd February, 2012. Retrieved from: https://physics.org.au/wp-content/uploads/cmm/2012/p5.pdfen_AU
dc.identifier.conferenceenddate3 February 2012en_AU
dc.identifier.conferencename36th Annual Condensed Matter and Materials Meetingen_AU
dc.identifier.conferenceplaceWagga Wagga, NSWen_AU
dc.identifier.conferencestartdate1 January 2012en_AU
dc.identifier.isbn978-0-646-57071-6en_AU
dc.identifier.urihttps://www.physics.org.au/wp-content/uploads/cmm/2012/p5.pdfen_AU
dc.identifier.urihttps://apo.ansto.gov.au/dspace/handle/10238/13677en_AU
dc.language.isoenen_AU
dc.publisherAustralian Institute of Physicsen_AU
dc.subjectAngular momentumen_AU
dc.subjectElementsen_AU
dc.subjectLaser spectroscopyen_AU
dc.subjectMagnetic propertiesen_AU
dc.subjectMetalsen_AU
dc.subjectOrganic compoundsen_AU
dc.subjectOrganic nitrogen compoundsen_AU
dc.subjectParticle propertiesen_AU
dc.subjectPhysical propertiesen_AU
dc.subjectSpectroscopyen_AU
dc.subjectTransition elementsen_AU
dc.titleThermal and pressure-induced spin crossover in a cobalt (II) imide complexen_AU
dc.typeConference Presentationen_AU
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